Influence of the olefin structure on the rate of hydroformylation and C=C bond hydrogenation in the presence of Co2(CO)8 as the catalyst precursor

Highly Regio‐ and Stereoselective Synthesis of Multialkylated Olefins through Carbozirconation of Alkynylboronates and Sequential Negishi and Suzuki–Miyaura Coupling Reactions

“…Our route to the tetraalkylated olefin 7 bearing four different substituents involved the aforementioned Suzuki–Miyaura cross‐coupling reaction of 4 and 1‐bromopropane (Scheme ). Compound 7 is the first example of a regio‐ and stereocontrolled tetrasubstituted olefin that contains four different linear unfunctionalized alkyl groups 32…”

Theoretical insights into the catalytic mechanism of propylene hydroformylation over Co–N–C materials

“…Hydroformylation is one of the most important homogeneous catalytic processes in industry, [1][2][3][4] since the corresponding products (aldehydes) are widely used in the synthesis of esters, alcohols, carboxylic acids, aliphatic amines and other fine chemicals. The homogeneous catalysts of hydroformylation mainly include tetracarbonyl hydrocobalt, cobalt catalysts modified by tertiary phosphine (e.g., tributyl phosphine), carbonyl rhodium phosphine catalysts (e.g., HRh(CO)(PPh 3 ) 3 ) and modified rhodium phosphine catalysts.…”