Influence of the Melt Treatment Method on the Properties of Cast Iron

Abstract

The article is devoted to studying the effect of liquid melt treatment with a substance having high affinity with hydrogen – lead-base silumin. Taking into account that gases (hydrogen, nitrogen and oxygen) are present everywhere, including alloys, a series of experiments was carried out on treating melt of blast furnace iron with substances having great affinity with hydrogen. It is established: when treating melt with lead-base silumin in the low-temperature test interval, there is a slight increase in the linear expansion coefficient (LEC) at 100°C, compared with the initial one, to 8.210-6, deg-1. In the temperature range of 100-150°C LEC decreases to a minimum value of 7.210-6, deg-1. In the average temperature range of 150-300°C, a sharp, anomalous increase is noticeable, compared with the initial one up to 15.5210-6, deg-1. When studying the microstructure of cast iron after processing the melt with lead silumin, the formation of ledeburite structure is stated. Samples treated with lead-base silumin were subjected to cementation by feeding water steam at 900°C for 1-5 hours. It should be noted that, in the temperature range of 50-150°C, the values of the linear expansion coefficient lie almost in a straight line in the entire field of study. The coefficient varies from 10.810-6, deg-1 at 50°C to 13.710-6, deg-1 at 450°C. Preliminary heat treatment of cast iron in the carburizer made by the Bondyuzhsky plant with water steam smoothes anomalies of LEC and increases its initial values, and grinds perlite and cementite as well. Subsequent quenching in water with a temperature of 1000°C significantly changes the linear expansion coefficient of cast iron. Hardening of samples after cementation sharply reduces the linear expansion coefficient in the test range of 150-200°C, and in the temperature range of 350-450°C negative values of LEC are observed. Thus, it can be concluded, that treating the melt with lead-base silumin, cementation in the medium of the carburizer made by the Bondyuzhsky plant and subsequent hardening leads to sharp changes of the linear expansion coefficient up to negative values. The identified properties suggest the possibility of using cast iron where it is necessary to constancy of LEC and there are no requirements for the weight of the product.

About the Anomalous Properties of Blast Iron Without Graphite Emissions

“…Принимая во внимание, что газы (водород, азот и кислород) присутствуют повсеместно [5][6][7][8][9][10][11][12][13][14][15][16], в том числе и в сплавах, разработаны различные способы обработки расплава доменного чугуна с целью изменения его коэффициента линейного расширения [17][18][19][20].…”