Influence of the Interpass Welding Temperature on Microstructure and Corrosion Resistance of Superduplex Stainless Steel SAF 2507

Abstract

The planning and execution of the adequate welding procedure for the superduplex stainless steel (SAF 2507 SDSS) in multiple passes is a complex technological task since thermal cycling may cause the precipitation of harmful phases, such as the sigma (σ) and chi (χ) phases. For this reason, technical standards limit the maximum interpass temperature (T.I.) in an extremely conservative manner at 100 °C. In order to investigate a possibly wider temperature range for this procedure, SAF 2507-SDSS tubes were subjected to autogenous Tungsten Inert Gas (TIG) welding with interpass temperatures ranging from 150°C to 400°C. The different welding zones were characterized by microscopy, Vickers microhardness, and polarization corrosion tests. The results indicated that in the Fusion Zone (FZ), columnar grains of ferrite were formed surrounded by allotriomorphic austenite (AA), besides intragranular austenite (AI) and Widmanstätten austenite (AW). The heat-affected zone (HAZ) had a lower ferrite content and was composed of equiaxed grains of ferrite, also surrounded by AA, besides AI and AW. Hardnesses varied between HV272 and HV293, regardless of the region or the interpass temperature used. Furthermore, the corrosion resistance has not been significantly affected by the interpass temperatures between 150 °C and 400°C.

Effect of Artificial Aging in the Microstructure and Corrosion Performance of Superduplex UNS S32750 Stainless Steel

“…This behavior is attributed to their balanced microstructure composed of 50% ferrite (α) and 50% austenite (γ). The dual-phase microstructure of DSS and SDSS allows enhanced corrosion performance, making the propagation of the corrosive process more difficult [1][2][3]. The alloying elements such as Cr, Mo, and N besides the manufacturing process guarantee the material's properties since the phase balance and precipitated-free microstructure are ensured [4][5][6].…”