Influence of Technological Parameters on the Composition and Properties of Petroleum Coke

Abstract

This study is devoted to studying the complex process of producing coke from heavy oil residues using previously developed experimental approaches and using analytical methods of analysis. The purpose of the study is to produce low-sulfur coke by thermal processing of heavy oil residues in the presence of waste motor oils. The resulting coke was analyzed by various physicochemical methods. The composition and structure of the resulting coke were studied using Raman spectroscopy methods. As a result of the analysis, the predominance of polyaromatic compounds and olefins in the coke composition was revealed. Electron microscopy techniques provided a visual representation of the microstructure and morphology of coke samples obtained both in the presence and absence of a recycling agent. Significant results were obtained by measuring the specific surface area of coke, which highlight the significant influence of temperature fluctuations on its characteristics of coke. It is noteworthy that the specific surface area of micropores varies significantly – from 16 to 600 m2/g. The results of the analysis of sulfur content showed the possibility of its thermal dehydration, which should lead to an improvement in the quality of coke. In addition, it has been shown that conducting the experiment in the presence of a recycling agent significantly increases the yield of coke and opens up prospects for more efficient use of heavy oil residues. Taken together, the results provide valuable insight into the intricacies of producing low-sulfur coke from heavy petroleum residues. In addition to industrial significance, this research also has environmental significance, since it proposes an approach that allows not only to maximize the use of secondary resources, but also to reduce the sulfur content in coke, which will help limit the environmental impact of industrial processes.