Composite materials with a high permittivity (high‐k) and low dielectric loss represent an important research direction for the rapid development of modern electronic. This article is about high‐k composite with low dielectric loss (dielectric constant is approximately 11, and dielectric loss is only 0.02 at 1 MHz and about 50 wt % of filler) based on a polytetrafluorethylene (PTFE) compounded with priderite (K1.46Ti7.2Fe0.8O16). The dielectric permittivity about ε' ≈ 103 and the dielectric loss of tgδ ≈ 2 have been found for filler content about 50 wt % (30 vol %) and, respectively, ε' ≈ 11 and tgδ ≈ 0.02 for 1 MHz. To produce filler, amorphous potassium polytitanate was synthesized by molten salt method, modified in aqueous solution of iron sulfate, crystallized at 700 °C and further treated in the aqueous dispersion of PTFE. The obtained product was pressured, dried and investigated by X‐ray diffraction and scanning electron microscopy. Dielectric properties of the composite with different ceramic filler content (1–90 wt %) were studied using impedance spectroscopy in the frequency range of 10−2 to 106 Hz. The influence of frequency on electric conductivity, permittivity, and dielectric losses was analyzed taking into account the experimental data on porosity, apparent density obtained for the composites. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48762.