“…These HEN coatings, with five or more principal target elements, are reported to possess many attractive properties. For example, the hardness of (AlCrTaTiZr)100−xNx [19,20], (AlCrSiTiV)100−xNx [21], (AlCrMoSiTi)100−xNx [22], and (AlMoNbSiTaTiVZr)100−xNx [23], (TiVCrZrHf)100−xNx [24], and (TiZrNbHfTa)100−xNx [25] all fall in the range of 32-36 GPa when the value of x is about 50. The hardness of (AlCrNbSiTiV)N is even higher (42 GPa), and still remains in the superhard level after vacuum annealing at 1000 °C for 5 h [26,27].…”