Influence of silver nanoparticle addition, porosity, and processing technique on the mechanical properties of Ba0.3Co4Sb12 skutterudites

Abstract

The thermoelectric skutterudite Ba 0.3 Co 4 Sb 12 is a promising candidate for waste heat recovery applications. Recently, it was demonstrated that the addition of silver nanoparticles (Ag NP ) to Ba 0.3 Co 4 Sb 12 increases both the thermoelectric figure of merit and electrical conductivity. This study is the first to examine the effect of Ag NP addition on the material's mechanical properties. This study also found that the Young's modulus, E, shear modulus, G, and bulk modulus, B, decreased linearly with increasing volume fraction porosity, P. Resonant ultrasound spectroscopy was employed to measure the elastic moduli, and Vickers indentation was used to determine the hardness, H, and fracture toughness, K C . Trends in the mechanical properties as a function of grain size, porosity, and the Ag NP are discussed in terms of the pertinent literature. While K C was independent of Ag NP addition, porosity, and grain size, both E and H decreased linearly with increasing porosity. In addition, this study is the first to identify (i) the Ag 3 Sb phase formed and (ii) the enhanced densification that occurs when the Ag NP is sintered with Ba 0.3 Co 4 Sb 12 powders, where both effects are consistent with the eutectic and peritectic reactions observed in the binary phase diagram Ag-Sb. These eutectic/peritectic reactions may also be linked to the enhancement of electrical conductivity previously observed when Ag is added to Ba 0.3 Co 4 Sb 12 . Also, similar beneficial eutectic/peritectic reactions may be available for other systems where conductive particles are added to other antimonides or other thermoelectric systems.

Mechanical properties of low-cost, earth-abundant chalcogenide thermoelectric materials, PbSe and PbS, with additions of 0–4 % CdS or ZnS

“…A nearly dense (P = 0.01) undoped PbS specimen was sintered for this study, but only by increasing the sintering temperature to 873 K. The enhanced densification of the Na-doped PbS specimens may indicate the Na dopant acts as a sintering aid. A previous study on a different TE material, Ba 0.3-Co 4 Sb 12 , showed the addition of metal particles, specifically 0.5 wt% Ag nanoparticles, may act as sintering aid [30]. In Ba 0.3 Co 4 Sb 12 , the Ag had a eutectic or peritectic reaction with Sb in the Ba 0.3 Co 4 Sb 12 [30] and a similar eutectic reaction may explain the enhanced densification in the Na-doped PbS specimens.…”

“…A previous study on a different TE material, Ba 0.3-Co 4 Sb 12 , showed the addition of metal particles, specifically 0.5 wt% Ag nanoparticles, may act as sintering aid [30]. In Ba 0.3 Co 4 Sb 12 , the Ag had a eutectic or peritectic reaction with Sb in the Ba 0.3 Co 4 Sb 12 [30] and a similar eutectic reaction may explain the enhanced densification in the Na-doped PbS specimens.…”

Tailoring the mechanical properties of thermoelectric lead telluride by alloying with non-doping calcium

“…Being highly doped semiconductors, thermoelectric materials are often very brittle and may show low fracture strengths. As a consequence, there have been some attempts in recent years to improve these mechanical properties in different classes of thermoelectric materials [7][8][9][10].…”

In-situ, non-destructive acoustic characterization of solid state electrolyte cells

“…Assuming a composite, this measured modulus after cycling, E c , would require an expected volume fraction of lithium metal, Vr. The Hashin particulate model, equation (4) [30][31][32][33][34], has previously been used to predict the E c of brittle (ceramic-like) composites with metal particle additions [34], and may also be used to determine expected volume fraction of lithium metal, Vr, from the measured composite modulus,…”