Influence of polycarbosilane composition on the properties of SiC/SiC composite fabricated by precursor infiltration and pyrolysis process

Abstract

A series of SiC/SiC composites were fabricated through the precursor infiltration and pyrolysis (PIP) process, using solid polycarbosilane (PCS) and liquid vinyl perhydrogen PCS (VHPCS) solutions as impregnating agents. The physicochemical characteristics of the SiC matrices derived from PCS and VHPCS were investigated and compared. The impact of the PCS composition on the microstructure, density, flexural strength, and modulus of the resulting SiC/SiC composites was also examined. As the VHPCS content increased to 60 wt%, the flexural strength of the composites gradually rose to a peak of 490.9 MPa before decreasing as the VHPCS proportion continued to increase. Meanwhile, the flexural modulus increased continually with the introduction of VHPCS. A possible mechanism is proposed to explain the different variations in flexural strength and modulus, taking into account the ceramic toughening principle and the distinct properties of PCS and VHPCS.