The manufacturing process of complex chinaware combining 3D printing technology with traditional technology is studied. In this process, the ceramic artwork was divided into several components. The manufacturing process of each part of the green body was selected according to the shape, and then all the green bodies were fitted together through the assembly structure and interpenetrating network binder for biscuit firing (debinding), glazing and glaze firing. The composition ratio of ceramic slurry was adjusted to make its sintering shrinkage be the same as that of traditional ceramic slurry. The experiments gave the technological process and parameters, and its structures were analyzed by field emission scanning electron microscope. The influence factors of glue discharge process, microstructure and pore distribution of the printing body after glue discharge were studied, aiming to provide a basis for the popularization and application of the process.