Influence of Molecular Structure of Ethylene Chloride on Ion-Association of Dissolved Salts

Vacuum Ultraviolet Absorption Spectra of Some Halogen Derivatives of Methane. Correlation of the Spectra1

“…For breaking a single bond it is assumed that CF4(g) = CFa(g) + F(g) -(14.65 e.v. + 2DF,)/4 (4) It is also assumed that the energy of the process CF4+(g) = CF3+(g) + F(g) -(14.65 e.v. + 2DFi)/4(5) is the same as in process (4).…”

Effect of selected anions and solvents on the electronic absorption, nuclear magnetic resonance, and infrared spectra of the N-retinylidenebutylammonium cation

“…O-Chlorophenyltrimethylammonium perchlorate has a dissociation constant ten times larger in 1,2-dichloroethane than in 1,1-dichloroethane (Ramsey and Colichman, 1947). Denison and Ramsey (1950) attributed this result to the ability of an ion to preferentially attract the gauche form of 1,2-dichloroethane.…”