N ANOCOMPOSITES of TiO 2 @Ni-doped or Co-doped graphene oxide (GO) have been sucessfully prepared and are employed for photocatalytic water splitting. TEM images showed doted nanostructure and scattered-appearance of Co, Ni with and TiO 2 nanoparticles on GO sheet. The XRD patterns proved the existence of the crystal planes of Ni, Co and TiO 2 nanoparticles on GO. Moreover, the absorption spectrum of the prepared samples showed a better percentage of absorption of the visible light upon introducing NiO or CoO. EDX analysis results confirmed the presence of Co, C, O, and Ti elements in the sample. Interestingly, both n-TiO 2 /p-NiO/GO and n-TiO 2 /p-CoO/GO heterojunctions photocatalysts improved the photocatalytic activity for water splitting nonetheless with different mechanisms. The n-TiO 2 /p-NiO/ GO photocatalyst showed a higher hydrogen production rate of 0.3 mmole/min/g than that of n-TiO 2 /p-CoO/GO. The generated e/h pairs in the TiO 2 part of the catalyst is kept through the effect of the electric field formed by the p-NiO/n-TiO 2 heterojunction while Co presence narrows the bandgap and promotes both hydrogen evolution reactions at the conduction and valence band of heterojunctions.