Abstract:In this report, high-frequency electric impedance spectroscopy was performed to investigate ionic transport through nanochannels. Special attention was focused on (i) conductance behaviors depending on the role of cation valence in three background electrolytes (XCln): monovalent 1-1 (K + and Cl − ), divalent 2-1 (Mg 2+ and 2Cl − ), and trivalent 3-1 (La 3+ and 3Cl − ), (ii) the effects of proton and bicarbonate ions on bulk and surface conductance, and (iii) the connected microchannel dimension (surface/heigh… Show more
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