Rubber Technology Centre Z n d i a n Znstitute of Technology Khar-agpur 721302, Z n d i aHysteresis loss has been measured at constant stress and constant strain, at various holding times under tensile deformation of natural rubber (NR) and styrene-butadiene rubber (SBR) vulcanizates filled with various loadings of carbon black filler. The effects of temperatures (25°C to 150"C), strain rates (3.78 X sec-' to 210 X sec-l) and strain levels (20% to 300%) have been studied. Hysteresis loss and hysteresis loss ratio increase with an increase in strain rate, filler loading, strain level and holding time. It decreases with an increase of temperature. However, higher hysteresis loss and hysteresis loss ratio are observed at constant stress than at constant strain. NR and SBR vulcanizates show similar behavior. Evidence has been produced for the existence of a distinct relaxation process that occurs within first 120 seconds of holding time at room temperature, This process becomes less important as the strain or the temperature is increased. However, at high temperature another distinct relaxation process has been observed. The activation energy has been found to be 66.3 kJ/mole for the rates at the higher holding time, while it has been found to be 17.3 kJ/mole for the rates at the lower holding time using the data of hysteresis loss at first cycle of 40 phr black fUed NR vulcanizates.(6-PPD), N-cyclohexyl thiophthaljmide (PVI) and 2-(4morpholinyl mereapto)-benzthiazole (BSM) were supplied by ICI Ltd., Rishra.The ingredients were mixed with rubber on a two roll mill (15 X lo-, m X 33 X lo-, m, Schwabenthan, Germany) at a temperature of 50°C and a friction ratio 1:l.l.The curing characteristics of the mixes were evaluated from a Rheometer R-100 according to ASTM D-2084-93. The molding of the tensile sheets (-2 mm thick) was carried out at a temperature of 150°C, 4 Mpa pressure and optimum cure time (tso in minutes) using a David Bridge Press, Castleton, Rocchdle, England.
Hysteresis loss and Hysteresis loss ratio:Hysteresis loss (Hy), defined as the amount of ener@ dissipated during cyclic deformation, was determined h m the areas W, (work done during extension) and W, (work done during retraction) when the specimens were stretched to varying extents and rates of elonga-tion and then allowed to retract at the same rate to the unstretched state