Influence of hydrothermal treatment on the microstructure and oxidation resistance of a Zn4B2O7·H2O (4ZnO·B2O3·H2O) coating for C/C composites

Yang, Liuqing; Huang, Jianfeng; Cao, Liyun; Fei, Jie; Ouyang, Haibo; Li, Cuiyan; Wu, Jianpeng; Hao, Wei

doi:10.1080/09603409.2016.1190899

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2018

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“…They can also be used as additives for lubrication and preservatives in wood composites . Among these reported zinc borates, ZnO·B 2 O 3 ·2H 2 O, 2ZnO·3B 2 O 3 ·3H 2 O, 3ZnO·5B 2 O 3 ·14H 2 O, and 6ZnO·5B 2 O 3 ·3H 2 O are very important, especially the 4ZnO·B 2 O 3 ·H 2 O, because of its low cost, good flame retardant property, and relatively high dehydration temperature for compounding with polymers at high temperatures.…”

Section: Introductionmentioning

confidence: 99%

Cyclic Utilization of Zinc Borate Mother Solution via a New Method

Liu

Dong

Nai

et al. 2018

Crystal Research and Technology

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Zinc borate mother solution is cycled to prepare 2ZnO·3B 2 O 3 ·7H 2 O, 3ZnO·5B 2 O 3 ·14H 2 O, and 4ZnO·B 2 O 3 ·H 2 O based on the properties of borate depolymerization. The results show uniform quadrilateral-prism-like and octahedron-like 2ZnO·3B 2 O 3 ·7H 2 O are synthesized at different temperatures. Flake-like 3ZnO·5B 2 O 3 ·14H 2 O is fabricated as reaction time prolonging, and 2ZnO·3B 2 O 3 ·7H 2 O changed into 3ZnO·5B 2 O 3 ·14H 2 O spontaneously. Meanwhile, resulting 2ZnO·3B 2 O 3 ·7H 2 O is investigated to fabricate high aspect ratio of 4ZnO·B 2 O 3 ·H 2 O whisker. Impressively, uniform 4ZnO·B 2 O 3 ·H 2 O whisker can be resynthesized by the filtrates of 2ZnO·3B 2 O 3 ·7H 2 O and 3ZnO·5B 2 O 3 ·14H 2 O via the zero-waste technology.

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