Influence of Er/Fe Substitution on Mg-Zn Nanoparticles’ Electromagnetic Properties and Applications

Abstract

Mg 0.8 Zn 0.2 Er x Fe 2-x O 4 (x = 0.00, 0.005, 0.01, 0.015, 0.02, and 0.025) nanoparticles made using the citrate gel autocombustion process were examined for their structure, morphology, and behavior. The single-phase cubic spinel structure was formed according to the diffraction pattern. Observations revealed that as the Er focus went from to 0.0 to 0.025, the average crystallite size ( D ) increased from 12.4 to 18.6 nm. The findings of the SEM and EDAX analyses reveal that the particles are uniform, with just a little amount of agglomeration and no impurity pickup. Nanoparticles from transmission electron microscopes (TEM) were present, the range from 12 to 19 nm. In IR spectroscopy using the Fourier transform (FTIR), nearly all the spinel ferrites presented generate two absorption bands that have wavelengths of around 400 cm and 600 cm. The BET surface area of the Er 3+ ion doping Zn-Mg ferrites rises from 23.860 m 2 /gm to 29.845 m 2 /gm. The TG–DTA analysis of the prepared samples confirms the thermal stability of the samples; the temperature ranges from 100 to 750 °C.The transition temperature (Seebeck coefficient) of the samples was studied using thermoelectric power (TEP) measurement studies, and it was found that all the samples showed N-type semiconductor behavior. With an increase in erbium concentration, DC conductivity decreases. At room temperature, the magnetic characteristics of hysteresis loops, squareness ratio (SQR), anisotropy constant (K), magnetic moment (), coercivity (Hc), saturation magnetization (Ms), and retentivity (Mr) were examined. When erbium concentration rises, the magnetic moment (B) increases. The saturation magnetization values were 288.4615 and 244.5266 emu/g, and squareness ratio values from 0.01554 to 0.03303 were observed. These materials are converted from hard permanent magnet materials to soft magnet materials.

Comparative Study of Rare Earth Nd and Sm Doping on the Structural, Morphological, Optical, Magnetic, and Electromagnetic Traits of Mg-Zn-Cu Spinel Nanoferrites

“…With the addition of Er content, there was a decrement in the value of M s (288.4615 to 244.5266 emu g −1 ) with an increment in the M r and H c . 22 Baburao et al, also prepared Mg 0.8 Zn 0.2 Gd x Fe 2−x O 4 (x = 0-0.025) ferrite samples using the citrate gel auto-combustion methodology. The size of crystallites and lattice parameters increases with an increase in the concentration of Gd.…”