The population of excited states of neon projectiles has been deduced from highresolution x-ray spectra. From the comparison of the satellite and the hypersatellite spectrum we conclude that the population of the outer shells is insensitive to the presence of either one or two K-shell vacancies. On the basis of a model of independent electrons the population distribution including states with filled K-shell can be estimated. The deduced mean charge states compare rather well with results obtained from beam analysis over a projectile energy range from 5 to 18 MeV.