“…Those methods were recently reviewed in . All alternative stabilisation approaches focus on reducing the residence times and the energy consumption or reaching higher stabilisations degrees followed by higher carbon yields . With e‐beam induced cyclisation, stabilisation degrees as high as 99 % could be reached .…”
Section: Process‐structure‐relations and Their Technical Potentialsmentioning
Several studies have shown the importance of carbon fibres (CF) for different high technology markets. In recent years, different fibre types with improved properties have been developed for those markets. Polyacrylonitrile (PAN) copolymers are the basic raw material (precursor) for these fibres in the predominant case. Improvements of the mechanical fibre properties have mainly been achieved by defect reduction during the manufacturing process. Thus, commercial carbon fibres with tensile strengths up to approx. 7000 MPa are currently available. It can be shown that the strengths can be further increased (in the direction of graphene properties) when the relationship between process conditions and defects due to manufacturing of the fibres is better understood. In this context, novel processes like electron beam crosslinking or UV‐activation have proven to be very promising. The article gives an overview about the current situation in the field of carbon fibres development and particularly shows recent shortcomings with respect to novel applications.
“…Those methods were recently reviewed in . All alternative stabilisation approaches focus on reducing the residence times and the energy consumption or reaching higher stabilisations degrees followed by higher carbon yields . With e‐beam induced cyclisation, stabilisation degrees as high as 99 % could be reached .…”
Section: Process‐structure‐relations and Their Technical Potentialsmentioning
Several studies have shown the importance of carbon fibres (CF) for different high technology markets. In recent years, different fibre types with improved properties have been developed for those markets. Polyacrylonitrile (PAN) copolymers are the basic raw material (precursor) for these fibres in the predominant case. Improvements of the mechanical fibre properties have mainly been achieved by defect reduction during the manufacturing process. Thus, commercial carbon fibres with tensile strengths up to approx. 7000 MPa are currently available. It can be shown that the strengths can be further increased (in the direction of graphene properties) when the relationship between process conditions and defects due to manufacturing of the fibres is better understood. In this context, novel processes like electron beam crosslinking or UV‐activation have proven to be very promising. The article gives an overview about the current situation in the field of carbon fibres development and particularly shows recent shortcomings with respect to novel applications.
“…After the atmospheric exposure, the remaining free radicals in the cyclic network structure readily react with oxygen in the air; thus, the formation of oxidized cyclic network structures is similar to that of the PAN treated by conventional thermal oxidative stabilization. The resulting oxidized cyclic network structures in the PAN were converted to graphitic carbon ones during carbonization [41,42]. The current-voltage (I-V) curves, electrical conductivity, and work function of the GCMs prepared by the carbonization of PAN microstructures at various temperatures are shown in Fig.…”
Section: Fabrication Of Gcms By Ion Beam Contact Lithography and Carbmentioning
“…For example, oxidative stabilization via consecutive irradiation treatments is regarded as an efficient and fast method to reduce the stabilization time and obtain a high yield of high-quality CFs. The effects of irradiations on the microstructures of PAN fibers via electron beam [2,3] and g-ray [4e6] have been investigated to evaluate the potential application of irradiation technology in producing CFs. Moreover, alternative method for the carbonization process such as microwave heating has also been considered as a more rapid and energy saving method compared with conventional heating [7,8].…”
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