Influence of Different Thermal Aging Conditions on Soot Combustion with Catalyst by Thermogravimetric Analysis

Abstract

Diesel particulates are deposited in the diesel particulate filter and removed by the regeneration process. The Printex-U (PU) particles are simulated as the diesel soot to investigate the influence of thermal aging conditions on soot combustion performance with the addition of catalysts. The comprehensive combustion index S, combustion stability index Rw and peak temperature Tp are obtained to evaluate the combustion performance. Compared with the PU/Pt mixtures of different Pt contents (2 g/ft3, 3.5 g/ft3, and 5 g/ft3), the 10 g/ft3 Pt contents improve soot combustion with the outstanding oxygen absorption ability. When the weight ratio of PU/Pt mixture is 1:1, the promoted effect achieves the maximum degree. The S and Rw increase to 8.90 × 10−8 %2min−2°C−3 and 39.11 × 105, respectively, compared with pure PU. After the thermal aging process, the PU/Pt mixture with a 350 °C aging temperature for 10 h promotes the soot combustion the best when compared to pure PU particles. It is not good as the PU/Pt mixture without aging, because the inner properties of soot and Pt/Al2O3 catalyst may have been changed. The S and Rw are 9.07 × 10−8 %2min−2°C−3 and 38.39 × 105, respectively, which are close to the no aging mixture. This work plays a crucial role in understanding the mechanism of the comprehensive effect of soot and catalyst on soot combustion after the thermal aging process.