Influence of char composition and inorganics on catalytic activity of char from biomass gasification

Abstract

This research investigates the catalytic properties of char which was recovered directly from a biomass gasifier. Poplar wood was gasified in steam and CO 2 environments in a fluidized bed reactor at temperatures ranging from 550 to 920°C. Char was composed of 85% carbon with concentrations of N, H, and S between 0.3% and 3%, depending on gasification conditions. The inorganics (Ca, K, Na, P, Si, Mg) were quantified, revealing that Ca was present in the highest concentration (0.5-1%), followed by K, ranging from 0.1% to 0.8%. The char had catalytic activity for decomposition of methane, which was used as a model molecule. The quantity of inorganics in the char was modified by acid washing in 16% aqueous HCl, which removed >95% of Ca, K, P, and Mg from the char. This resulted in an 18% decrease in the quantity of methane reacted compared to the original char sample, demonstrating that inorganics, which only make up approximately 2% of the char, play a significant role in its catalytic activity for methane cracking reactions. In addition, carbon was found to play an important role in the catalytic activity of the char, both as a catalyst and a support on which the inorganics were dispersed. The activity of carbon free ash was approximately 90% lower than that of char, and deactivated to have no measurable activity after 45 min on stream, demonstrating the importance of carbon and dispersed inorganics for catalytic activity. When char was heated to 1000°C in N 2 , inorganics and oxygen migrated to the surface of the char, covering the carbon surface in a metal oxide layer. This decreased the catalytic activity by approximately 40%. Acidic (e.g. carboxylic, lactones) and basic (e.g. carbonyl, pyrone) oxygen functional groups were identified on the char surface. However, acidic oxygen groups desorbed at reaction temperatures, so these groups likely do not participate in cracking reactions.

Production and utilization of biochar: A review

“…As shown in Table 11, the cations in the biomass reside in biochar after the biochar production processes [145,146]. When biochar is applied to soil, the basic cations contained The CEC of the soil increases with increasing charge density in soil (per unit surface area) and with increasing soil surface area that can adsorb cations [147].…”

Catalytic characteristics of the pyrolysis of lignite over oil shale chars

“…The main difference between the FTIR spectra profiles was that sample FC-450 had a slightly higher ACH 2 peak at $2931 cm À1 and a lower SiAOASi peak at 1110 & 798 cm À1 . The FTIR profiles confirmed the presence of oxygen functional groups on the surface, and showed that there were aluminosilicate on the char surface, which was the chief constituents in molecular sieve [13].…”

“…It has been reported that oxygen functional groups can play a role in catalytic activity of carbon materials [13]. Therefore functional groups on the char surface were studied.…”

“…In general, oil shale char is used for production of cement and concrete, asphalt shingle, quarry-fill and sludge stabilization, soil treatment for agricultural purpose, while the large portion is dumped in landfills [8]. In recent years, char, or similar materials such as activated carbon, has been reported to have catalytic activity for reforming or cracking of hydro carbons [9][10][11][12][13].…”

“…Two model-free methods were used to determine the kinetic parameters which represent the pyrolysis of ignite [14]. Furthermore the oxygen functional groups, minerals composition, inorganic oxides and selected trace metals (Co, Cu, Cr and Zn) may affect the catalytic activity and are also studied here [13].…”