a b s t r a c tThe influence of alloying on the ignition and flammability was studied. One end of a cylindrical specimen was exposed to a free diffusion flame. Ignition required at least partial melting. Burning extinguished once the flame was withdrawn. Specimen tips of pure Mg, AZ61, and AZ91 ignited upon prolonged flame exposure. There was smouldering and delayed ignition for Mg-1Y. There was no ignition for Mg-5Y specimen tips, attributed to a protective surface oxide containing Y. The results indicate that (i) vigorous burning requires a continued supply of Mg vapour, and (ii) a critical alloy concentration is required to change ignition behaviour.