The electrochemical behavior of non-modified, Pt-modified, and Pt/polyaniline-modified carbon fiber textile electrodes was studied through a series of electrolyses, under potentiostatic conditions, on an amaranth/sulfuric solution in the presence or absence of chloride ion. The morphology of the dispersed Pt, PANI, and PANI/Pt coatings was analyzed by scanning electron microscopy. Scanning electrochemical microscopy confirmed that the textile surface was effectively modified by the electrocatalytic material. Color removal reached values above 90 % in both electroreduction and electrooxidation processes. The amaranth electroreductions carried out with the nonmodified electrode showed better charge efficiency than those with the Pt-modified textile electrode. The electrooxidations with Pt-modified textile electrodes showed a significant reduction in electrolysis time. Ultraviolet-visible and Fourier transform infrared with attenuated total reflection spectra enabled the electrochemical behavior of the non-modified and Pt/PANI-modified electrodes to be distinguished.