Influence of Carbyne Content on the Mechanical Performance of Nanothick Amorphous Carbon Coatings

Abstract

This study concerns the evaluation of the coefficient of friction, at different temperatures, of amorphous carbon thin films, deposited onto nanocrystalline sputtered copper coatings by clean-technology rf magnetron sputtering. The aim is to access the capacity of carbon thin films, with different contents of sp2 and sp1 bonds, to act as a solid lubricant for copper surfaces. Raman spectroscopy revealed that all the as-deposited coatings consist of amorphous carbon with low defect content and decreasing carbyne concentration with increasing thickness. The tribological tests at 25 °C and 200 °C revealed that, for the higher temperature, the 15 nm carbon coating present 0.001 friction coefficients at 2 N load. Overall, the study presents a one-step technology for the greener production of solid lubrication systems for micro- and nano-components, avoiding the environmental impact of lubricants.

Structure and Characterization of Vacuum Arc Deposited Carbon Films—A Critical Overview

“…The films are usually completely sp 2 -bonded. Sometimes, minor contents of carbynelike sp 1 bonds have been observed [96]. At not too high deposition temperatures (typically below 200 °C), the impinging carbon atoms have only a limited surface mobility.…”