The paper presents a study of the stability of cellulose and synthetic papers exposed to various methods of accelerated ageing. Particular consideration was given to the optical and mechanical stability of six paper samples (one film synthetic paper, two fibre synthetic papers, one lignin-free paper of higher quality and two security cellulose papers), which have undergone changes during accelerated ageing. The papers were artificially aged using standard techniques of accelerated ageing, e.g. moist-heat (80 °C and 65% RH), dry-heat (105 °C) and treatment with a xenon arc lamp (35 °C CT, 50 °C BST, 35% RH). The ageing was performed for the periods of 1, 2, 3, 6 and 12 days. The changes in the optical (ISO brightness, Yellowness Index), surface (roughness, paper topography) and mechanical stability (zero-span tensile strength, elongation at break, folding endurance) of papers were measured during the periods of accelerated ageing. The results show that the differences between synthetic and cellulose papers exist. On average, the dry-heat ageing had the highest influence on ISO brightness and Yellowness Index on synthetic papers, while the treatment with a xenon lamp had the strongest influence on cellulose papers. A comparison of mechanical properties showed that synthetic papers are more durable than cellulose paper; they had higher zero-span tensile strength and folding endurance, and showed substantially better ageing resistance to dry-heat and moist-heat accelerated ageing than cellulose papers. It was also noticed that the surface roughness increased after all three accelerated ageing processes.