Influence of adhesion promoters on the aging characteristics of optical fibers in water

Leclercq, J. M.; Breuls, Anton H. E.

doi:10.1117/12.187450

Cited by 2 publications

(1 citation statement)

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“…They explained the n-value increase by the silica surface smoothening via a pit blunting process that was earlier suggested by Abe et.al.4 In other studies, the increase in strength and dynamic fatigue was suggested to result from a change ofthe chemical environment at the silica surface due to the inner primary coating chemistry and an enhanced optimized adhesion between the silica surface and the coating. 5 Furthermore, it has also been suggested that the fiber static fatigue can be improved by a reduction in the moisture permeability of coating materials,6 by a modification of the primary coating structure with colloidal silica particles7 or by generating a residual high-strength gel layer at the silica surface via silica surface corrosion.8 it is often observed that the static fatigue n-value is slightly higher than the dynamic fatigue nvalue although the physical basis ofthis disparity is not understood yet. It is also widely believed that the fiber strength increase during high-temperature aging in air results from a substantial hardening of coating materials.…”

Section: Introductionmentioning

confidence: 97%

<title>Mechanical behavior of coated fused silica optical fibers aged at elevated temperature in air and filling compound</title>

Volotinen

Gebizlioglu

1996

SPIE Proceedings

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In this report, we present an experimental analysis of the mechanical behavior of fused silica standard telecommunication fibers aged in hot air and hot filling compound. Our measurements at standard room temperature conditions after the aging treatments indicated tensile strength increases of up to 5 % at 85°C and 1 5 % in filling compound after one-to six-month aging. The dynamic fatigue for the fibers aged in the filling compound also improved (n-values from 17 -20 to 25 -30) in parallel with the fiber strength while the fiber static fatigue tests gave large n-value increases from 30 to 140. In order to examine the effects of the aging treatments on the fiber coatings, we used dynamic mechanical analysis to measure the coating mechanical properties, storage modulus E' and loss tangent tan ö. In general, we have found that aging in hot air and in the filling compound results in a significant decrease in E' and increase in tan ö, thereby suggesting an aging-related increase in the capacity ofthe coating to absorb substantial amounts of mechanical energy. A qualitative theoretical analysis ofthe coating contribution to the fiber crack growth and mechanical behavior in conjunction with our experimental results suggests that the coatings' ability to absorb more mechanical energy during aging contributes to increased fiber strength and improved fatigue behavior. Thus, our results to date provide the first experimental evidence for that a fiber coating can stabilize cracks on fused silica surfaces and contribute in a significant way to fiber mechanical behavior.

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Section: Introductionmentioning

confidence: 97%