Influence of additives fluoride and phosphate on the electrochemical performance of Mg–MnO2 battery

Xu, Jing; Yang, Qiaoling; Huang, Chunli; Javed, Muhammad Sufyan; Aslam, Muhammad Kashif; Chen, Changguo

doi:10.1007/s10800-017-1074-1

Cited by 16 publications

(3 citation statements)

References 27 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Furthermore, adding additives to the electrolyte is known to be a convenient and effective method. For example, the self-discharge capacity is significantly increased by adding water soluble graphene to NaCl solution.14 Jing et al 15 found that when NaF and Na 3 PO 4 were used as additives to electrolyte Mg-MnO 2 cell demonstrated an excellent discharge performance. And sodium dodecylbenzenesulfonate (SDBS) as a good organic inhibitor can work together with the Na 2 SiO 3 on the AZ31 magnesium alloy in 1% NaCl.…”

mentioning

confidence: 99%

“…9,10 There are numerous efforts to reduce selfcorrosion of magnesium, focusing either on how to improve anode behaviors [11][12][13] or how to optimize electrolyte composition. 14,15 Compared to studies for anode improvement, there are few studies aimed at electrolyte optimization. Furthermore, adding additives to the electrolyte is known to be a convenient and effective method.…”

mentioning

confidence: 99%

See 1 more Smart Citation

Investigation of Sodium Phosphate and Sodium Dodecylbenzenesulfonate as Electrolyte Additives for AZ91 Magnesium-Air Battery

Wang

et al. 2018

J. Electrochem. Soc.

View full text Add to dashboard Cite

This paper reports on the improvement of discharge performances of magnesium-air batteries by adding sodium phosphate and sodium dodecylbenzenesulfonate to sodium chloride aqueous solution. Four different electrolytes are tested. Results obtained show that the discharge potential and anode utilization of magnesium-air battery increase significantly with addition of the additives. With an electrolyte of 3.5 wt% sodium chloride+0.5 g · L −1 sodium phosphate, the discharge potential increases from 1.120 V to 1.150 V and the anode utilization increases from 44.1% to 49.1%. The self-corrosion rate of anode has a tendency to decrease with addition of the additives. In solution of 3.5 wt% sodium chloride+0.5 g · L −1 sodium dodecylbenzenesulfonate +0.5g · L −1 sodium phosphate, the self-corrosion is low and the inhibition efficiency can reach 95.2%. Magnesium-air (Mg-air) battery plays an increasingly significant role in power source energy and storage devices.1,2 There are lots of advantages of Mg-air battery, such as high theoretical potential (3.09 V), high specific energy density (6.8 kWh · kg −1 ), neutral electrolyte, environmental friendliness, and low cost. 3-5Although Mg-air battery has a promising future, there are still some problems remarkably limiting its development and delaying its application in daily life. One of the major problems is anodic polarization during battery discharge. [6][7][8] As the total reaction of Mgair battery (Eq. 1) shows:The discharge product is magnesium hydroxide which has a tendency to attach to the surface of anode. It can reduce the reactionsurface area leading to a decrease of discharge potential when battery discharges in a constant-current mode. As we all know, the potential of Mg is −2.37 V (vs · SHE) and it can react spontaneously with aqueous solution according to the following equation:This wasteful self-corrosion leads to low utilization efficiency during discharge process. 9,10 There are numerous efforts to reduce selfcorrosion of magnesium, focusing either on how to improve anode behaviors [11][12][13] or how to optimize electrolyte composition. 14,15 Compared to studies for anode improvement, there are few studies aimed at electrolyte optimization. Furthermore, adding additives to the electrolyte is known to be a convenient and effective method. For example, the self-discharge capacity is significantly increased by adding water soluble graphene to NaCl solution.14 Jing et al. 15 found that when NaF and Na 3 PO 4 were used as additives to electrolyte Mg-MnO 2 cell demonstrated an excellent discharge performance. And sodium dodecylbenzenesulfonate (SDBS) as a good organic inhibitor can work together with the Na 2 SiO 3 on the AZ31 magnesium alloy in 1% NaCl. 16Although electrolyte is one of the most crucial factors, additive research is few comparing the anode materials. Up to now, Mg-air batteries with Na 3 PO 4 and SDBS as additives have never been studied. It is known that sodium chloride aqueous solution (3.5% NaCl) is the most suitable electrolyte for Mg-air batt...

show abstract

mentioning

confidence: 99%

mentioning

confidence: 99%

Investigation of Sodium Phosphate and Sodium Dodecylbenzenesulfonate as Electrolyte Additives for AZ91 Magnesium-Air Battery

Wang

et al. 2018

J. Electrochem. Soc.

View full text Add to dashboard Cite

show abstract

“…According to our previous work (Xu et al, 2017), the AZ31B Mg alloy (3.0 wt% Al, 1.0 wt% Zn, 0.2 wt% Mn, and 96.8 wt% Mg) was purchased from Wuxi Xinbiao Metal Material Co. Ltd. in China. The Mg alloy was sheared into an appropriate size of 1 × 1 cm with a thickness of 0.6 cm, then embedded with electric conductive copper wire, and encapsulated with epoxy resin in quick succession.…”

Section: Experiments Chemicals and Materialsmentioning

confidence: 99%

Electrochemical behavior of Mg electrode in sodium salt electrolyte system

Zhang

Zhu

et al. 2022

Front. Chem.

View full text Add to dashboard Cite

A suitable electrolyte is crucial to enhancing the electrochemical performance of magnesium (Mg) batteries. Here, the influence of Na2SiO3 on the electrochemical behavior of AZ31B Mg alloy in the Na2SO4-NaNO3 composite electrolyte was investigated. The results revealed that the activation potential of the AZ31B Mg alloy first represented a negative shift and then a positive shift with the increase in Na2SiO3. The most negative activation potential (−1.51 V) and the lowest polarization (−3.20 V) were found when 6 mM of Na2SiO3 was added; no discharge hysteresis was observed, and the polarization resistance value (R1) was 3,806 Ω. After 24 h immersion in the composite electrolyte with Na2SiO3, more and wider cracks appeared on the alloy surface, where a thick, dense film was formed, showing excellent discharge performance and corrosion resistance.

show abstract

A Low‐Cost and Recyclable Mg/SOCl₂ Primary Battery Via Synergistic Solvation and Kinetics Regulation

Geng

Yuan

et al. 2022

Adv Funct Materials

View full text Add to dashboard Cite

Lithium/thionyl chloride (Li/SOCl2) primary batteries are appealing power solutions because of their remarkable electrochemical performances. However, their mass applications are hindered by the challenges in sustainability, cost and safety concerns owing to the employed Li chemistry. Here, magnesium (Mg) chemistry is shown as a promising alternative through synergistic optimization of electrolyte solvation and electrode reaction kinetics. The first Mg/SOCl2 primary battery yields surprisingly high specific capacities up to ≈14 000 mAh g−1 at a decent discharge voltage of ≈1.67 V, which outperforms the state‐of‐the‐art Mg‐based primary batteries. In addition, it retains almost 100% of the original capacity after 20‐day reservation. The impressive battery performances are originated from the stabilized MgCl2 formation on high‐surface‐area carbon cathode and suppressed Mg anode corrosion via the Mg‐induced solvation effect. Mg/SOCl2 primary batteries are promising candidates for low‐cost and recyclable power supplies, and they thus open new avenues for the development of sustainable battery chemistries.

show abstract

Influence of additives fluoride and phosphate on the electrochemical performance of Mg–MnO2 battery

Cited by 16 publications

References 27 publications

Investigation of Sodium Phosphate and Sodium Dodecylbenzenesulfonate as Electrolyte Additives for AZ91 Magnesium-Air Battery

Investigation of Sodium Phosphate and Sodium Dodecylbenzenesulfonate as Electrolyte Additives for AZ91 Magnesium-Air Battery

Electrochemical behavior of Mg electrode in sodium salt electrolyte system

A Low‐Cost and Recyclable Mg/SOCl₂ Primary Battery Via Synergistic Solvation and Kinetics Regulation

Contact Info

Product

Resources

About

Influence of additives fluoride and phosphate on the electrochemical performance of Mg–MnO2 battery

Cited by 16 publications

References 27 publications

Investigation of Sodium Phosphate and Sodium Dodecylbenzenesulfonate as Electrolyte Additives for AZ91 Magnesium-Air Battery

Investigation of Sodium Phosphate and Sodium Dodecylbenzenesulfonate as Electrolyte Additives for AZ91 Magnesium-Air Battery

Electrochemical behavior of Mg electrode in sodium salt electrolyte system

A Low‐Cost and Recyclable Mg/SOCl2 Primary Battery Via Synergistic Solvation and Kinetics Regulation

Contact Info

Product

Resources

About

A Low‐Cost and Recyclable Mg/SOCl₂ Primary Battery Via Synergistic Solvation and Kinetics Regulation