Influence of Additional Micro-Sized Particles of Dy–Nd–Cu–Al on Magnetic Properties of Sintered Nd–Fe–B Magnets

Abstract

In this work, we investigated the influence of concentration of the additional micro-sized particles of Dy40Nd30Al30 and Nd40Cu30Al30 on magnetic properties of the sintered Nd16.5Fe77B6.5 magnets. The additional particles with size in the range of 1–3 μm were prepared by ball milling method and then mixed into micrometer Nd16.5Fe77B6.5 master powder with different weight fractions before magnetic anisotropic pressing, vacuum sintering and annealing. The results show that the coercivity of the sintered Nd–Fe–B magnets can be improved considerably by introducing additional particles to the grain boundaries. The improvement of the coercivity Hc of the magnets is clearly dependent on the composition and concentration of the additional microparticles. The Hc increases linearly from 8.5 kOe to 17 kOe with increasing the weight fraction of the Dy40Nd30Al30 microparticles from 0 to 5%. Meanwhile, the coercivity of the magnet reaches a maximum value of 11.7 kOe with 4 wt% addition of Nd40Cu30Al30. The quite high maximum energy products, (BH)max > 30 MGOe, were also obtained for the magnets added with the microparticles. The obtained hard magnetic parameters of the magnets can be applied in practice.

Coercivity Enhancement of Sintered Nd–Fe–B Magnets by Intergranular Adding Micro-Structured Dy–Nd–Pr–Al–Cu Powder

“…Notably, the squareness of the hysteresis loops of the added magnets is better in comparison to that presented in our previous studies. 24,26) This can be explained by the improvement of microstructure of the added magnets such as uniform grains and smooth grain boundaries 5. The obtained results reveal that the grain size of the magnet after sintering and heat treatment, which is in range of 610 µm, is larger than that of the as-milled powder.…”