Ammonia is primarily used as nitrogenous fertilizer and as a raw material of inorganic compounds including nitric acid, ammonia salts, cyanide and organic compounds, such as amines, sulfanilamide and so on. In addition, ammonia is also an excellent refrigerant. Since ammonia is a key raw material for industry and agriculture, the process of ammonia synthesis has an extremely important position in any economy. During ammonia synthesis in nitrogenous fertilizer plant for production of nitrogenous fertilizer and other products, the major reactions of production and purification of synthesis gas and the synthesis of ammonia, all the carried out over different catalysts (Prajapati, R. P., Sharma Anand and Tiwari, D. R., 2010) . At least eight kinds of catalyst used in the whole process, where natural gas or naphtha is used a feedstock and steam reforming is used to produce synthesis gas. These catalyst, are Co-Mo hydrogenation catalyst, zinc oxide desulfurizer, primary and secondary, steam reforming catalysts, high and low temperature shift catalysts, methanation catalyst and ammonia synthesis catalyst etc. In every catalytic operation, activity of the catalyst gradually decreases. Due to structural changes, poisoning, or deposition of extraneous material. A catalyst, which can no longer perform its original duty is referred to as "spent catalyst". In such cases fresh catalysts have to be substituted and the spent catalyst will be discarded as solid waste material. Disposal of spent catalyst is a problem as it falls under the category of hazardous industrial waste. Environmental laws concerning spent catalyst disposal have becomes increasingly more serve in recent years. Metals such Ni, Mo, Fe, Co, Cu, Zn and Cr present in the spent catalyst can leached by water after disposal and pollute the