“…The piezoelectric coefficient e 11 is the largest in the Janus HfGeN 3 H monolayer (2.77 × 10 −10 C m −1 ), while the magnitude of d 11 is the largest in the HfGeAs 3 H monolayer (−1.78 pm V −1 ). These values are smaller than the corresponding piezoelectric coefficients in structurally similar compounds such as MoGeZ 3 H 55 and WSiZ 3 H. 56 More importantly, the out-of-plane piezoelectric coefficients in Janus structures are non-zero, resulting from the breaking of mirror symmetry due to different atoms at the two surfaces of the material. Specifically, the values of e 31 are 0.32 × 10 −10 , 0.14 × 10 −10 , and 0.02 × 10 −10 C m −1 for the HfGeN 3 H, HfGeP 3 H, and HfGeAs 3 H monolayers, respectively.…”