2003
DOI: 10.1103/physrevlett.91.227201
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Induced Magnetic Ordering by Proton Irradiation in Graphite

Abstract: We provide evidence that proton irradiation of energy 2.25 MeV on highly oriented pyrolytic graphite samples triggers ferro- or ferrimagnetism. Measurements performed with a superconducting quantum interferometer device and magnetic force microscopy reveal that the magnetic ordering is stable at room temperature.

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Cited by 801 publications
(651 citation statements)
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“…For example, magnetism has experimentally been reported both in nanographene [58,59,60], and in graphite in the presence of disorder [61] or grain boundaries [62], although pristine graphene has not been found to be either magnetic [63] or gapped [64,20]. Theoretically, on-site Coulomb repulsion exceeding U > 3.9t has been found to give an antiferromagnetic state in undoped graphene in quantum Monte Carlo simulations [15,17].…”
Section: Electron Interactions In Graphenementioning
confidence: 99%
“…For example, magnetism has experimentally been reported both in nanographene [58,59,60], and in graphite in the presence of disorder [61] or grain boundaries [62], although pristine graphene has not been found to be either magnetic [63] or gapped [64,20]. Theoretically, on-site Coulomb repulsion exceeding U > 3.9t has been found to give an antiferromagnetic state in undoped graphene in quantum Monte Carlo simulations [15,17].…”
Section: Electron Interactions In Graphenementioning
confidence: 99%
“…Ion irradiation can be used to introduce structural defects in graphene and other carbon allotropes 16 , and provides a versatile tool for manipulating their physical properties 7,[17][18][19][20][21][22] For this purpose, proton irradiation, in particular, attracts much interest due to the observed irradiation-induced magnetism in graphite and graphene [23][24][25][26][27][28][29] , which was attributed to defects, e.g., vacancies and H species 24 . However, an atomic-resolved determination, e.g.…”
mentioning
confidence: 99%
“…It is still unclear whether defects can be generated at a higher proton energy. Moreover, to mimic proton irradiation in various experiments 23,28,29 where fast H + ions with kinetic energy ranging from a few hundred keV to a few MeV were used, it would be very valuable to extend the simulations to that energy range and also explore the effect of the charge state of the projectile.…”
mentioning
confidence: 99%
“…The existence of π-electron magnetism in pure carbon has now been widely accepted (see e.g. [40,41]). On the theoretical side, it is well known that magnetic instabilities exist at specific graphene edges [42,43,44,45], in defective graphene [46] and nanotubes [47].…”
Section: Introductionmentioning
confidence: 99%