Induced Magnetic Field Used to Detect the Sigma Phase of a 2205 Duplex Stainless Steel

Abstract

Sigma phases are formed due to heat treatments and/or welding processes during the solidification stage, and they are responsible for embrittlement of duplex stainless steels. Only a small amount of this phase promotes unfavorable mechanical properties and liability to corrosion. In this work, a new affordable approach to detect and follow-up the kinetics of the sigma phase transformation is evaluated. The measurements are based on an induced magnetic field generated through the interaction between an external magnetic field and the microstructure under study. To validate this approach, the induced magnetic field values are compared with the values of the Charpy impact energy, and the sigma phase is assessed by optical microscopy. Moreover, surface fractures are analyzed by scanning electron microscopy and X-ray diffraction. The results from the 2205 duplex stainless steel used show that there is a direct relation among the impact energy, fracture mechanism and induced magnetic field. The method proved to be able to follow up the embrittlement of the DSS successfully. Moreover, the results confirm that the presence of a sigma phase can be studied based on 4 an induced magnetic field, even when in low amounts, and that a critical threshold value can be defined to monitor structures in service.

Characterization of the Native Passive Film on Ferrite and Austenite Phases of Sensitized 2205 Duplex Stainless Steel

“…For instance, it has been reported that DSSs, upon exposure to temperatures between 600°C and 1050°C, form secondary phases. 1 These secondary phases such as σ, χ and R phases, secondary austenite, carbides (M 7 C 3 , M 23 C 6 ), and nitrides (Cr 2 N) can form at the ferrite/austenite phase boundaries or inside austenite and ferrite 1,[22][23][24][25][26][27] due to the high diffusion rate of Cr and Mo especially in ferrite at high temperatures. Diffusion of alloying elements, particularly Cr in z E-mail: a.davodi@um.ac.ir; saman.hosseinpour@fau.de such cases may lead to the formation of Cr depletion zones in the microstructure of DSS, which increases the susceptibility of the alloy to several localized corrosion attacks such as pitting corrosion, stress corrosion cracking, and intergranular corrosion.…”