Induced Electronic and Thermal Effects of 86 MeV Nickel Ions in Bisphenol-A Polycarbonate

Abstract

Bisphenol-A polycarbonate films were irradiated with 86 MeV swift heavy nickel ions at varying fluences, ranging from 110 11 to 110 13 ions cm 2 , under vacuum at room temperature, to analyze the induced electrical and thermal modifications. AC conductivity measurements and UV-visible spectroscopy, Fourier transform infra-red (FTIR) spectroscopy, thermo-gravimetric analysis (TGA), differential scanning calorimetry (DSC) and X-ray diffraction (XRD) techniques were applied to analyze the changes. A significant, exponential increase in conductivity at higher frequency was observed with the increase of nickel ion fluence. UV-visible analysis corroborated the results of the AC conductivity measurement, revealing the increase in size of the carbon clusters embedded in the polymer network, with the increase of heavy ion fluence. FTIR analysis revealed the formation of alkene and alkyne end groups at higher doses, which further supported Downloaded by [University of Nebraska, Lincoln] at 02:20 15 June 2016 ACCEPTED MANUSCRIPT ACCEPTED MANUSCRIPT 2 the suggestion that the variation in electrical properties induced by the ion irradiation of the polymer was due to development of a carbonaceous phase inside the polymer due to the irradiation. Thermal analysis, i.e. TGA and DSC patterns, showed that chain-scission was the leading phenomena in the heavy ion irradiated polycarbonate samples, resulting in degradation of their thermal stability.