ABSTRACT. Thermal ions in spherical tokamaks have two adiabatic invariants: the magnetic moment and the longitudinal invariant. For hot ions, variations in magnetic-field strength over a gyro period can become sufficiently large to cause breakdown of the adiabatic invariance. The magnetic moment is more sensitive to perturbations than the longitudinal invariant and there exists an intermediate regime, super-adiabaticity, where the longitudinal invariant remains adiabatic, but the magnetic moment does not. The motion of super-adiabatic ions remains integrable and confinement is thus preserved. However, above a threshold energy, the longitudinal invariant becomes non-adiabatic too, and confinement is lost as the motion becomes chaotic. We predict beam ions in present-day spherical tokamaks to be super-adiabatic but fusion alphas in proposed burning-plasma spherical tokamaks to be non-adiabatic.Consider a charged particle, with mass m and charge q, gyrating with speed v in a magnetic field, with field strength B. Assume axi-symmetric toroidal geometry with coordinates (R, φ, Z). The motion preserves the energy E (because the Lorentz force performs no work) and canonical toroidal momentum P φ (because the toroidal coordinate is ignorable). There is no third exact constant of motion, but the normalized magnetic momentwhere v ⊥ is the velocity component perpendicular to the magnetic field (v 2 ⊥ = v 2 −v 2 , v = v·B/B) and B 0 is the on-axis magnetic field, is an adiabatic invariant, i.e. as long as the variation in the magnetic field experienced by the particle during one gyro period is small, Λ oscillates at the gyro frequency around a constant average. If we introduce the adiabaticity parameter, ε, the condition of slow (adiabatic) variation becomes ε = ̺ |∇B| B ≪ 1 , where the gyro radius ̺ = v ⊥ /Ω, with the gyro frequency Ω = |q|B/m. The approximate constancy of the magnetic moment was first pointed out by Alfvén [1]. Just as the magnetic moment is associated with the gyro motion, a second adiabatic invariant is associated with the slower drift motion:When ε ≪ 1, there are thus three constants of motion, one for each degree of freedom, i.e. the motion is integrable, the orbits are quasi-periodic and, in the absence of collisions, a particle will be eternally confined. As the perturbation grows and ε 1, a dramatic change in the character of the motion, from bounded to unbounded, will occur, as the adiabaticity breaks down, the third constant of motion is lost, the motion becomes non-integrable, and the orbits become chaotic. This process was first investigated numerically [3] and later fully explained by the rigorous KAM (Kolmogorov, Arnold & Moser) theory [4]. Subsequently, Chirikov provided an approximate, but more practical, approach when he introduced his semi-empirical resonance-overlap criterion and the standard mapping [5]. In the Chirikovian model, the breakdown of adiabaticity is caused by strong nonlinear resonance between the periodic motions occurring on different timescales.