The converter transformer is a key equipment in high voltage direct current (HVDC) transmission system. Its oil-paper insulation system in the valve winding and outlet bushing experiences AC, DC, AC/DC, and transient impulse voltages simultaneously. The oil contamination problem is more serious under DC electric field. Therefore, it is significant to investigate the characteristic of particles motion and accumulation under DC electric field. In this paper, first, the movement and accumulation behavior of fiber particles and copper particles in mineral oil and natural ester were recorded and simulated. Then, the influence of fiber and copper particles on the oil conductivity was analyzed. Finally, the DC breakdown strength of mineral oil and natural ester with different particles concentration was compared. Results show that the movement speed of copper particles was larger than that of fiber particles. Fiber impurities were easy to form bridges in mineral oil, while there was no impurity bridge in natural ester. The current density of mineral oil containing particles is larger than that of the natural ester at the same testing time. The DC 50% probability breakdown voltages of oil samples containing fiber and copper particles decreased linearly with the increase of particle concentration, and the decrease rate of DC 50% probability breakdown voltages of oil containing copper particles were faster than that of oil containing fiber particles. Compared to pure mineral oil, the DC breakdown voltages corresponding to 50% probability of contaminated mineral oil showed a decrease from 11.9% to 22.5% when the fiber particle concentration increased from 0.001% to 0.012%. The DC 50% probability breakdown voltages of contaminated mineral oil with copper particles decreased from 23.8% to 45.0% when the particle concentration increased from 0.1 g/L to 1.5g/L. However, the decline range of the figures for natural ester contaminated by fiber or copper particles showed a smaller drop.Energies 2020, 13, 1818 2 of 16 requirements of green and environmentally friendly insulating oil [1][2][3][4][5]. Since 1990s, researchers have carried out a series researches on the application of natural ester to replace mineral oil. There are more than one million natural ester transformers in operation in the world, with voltage levels ranging from 10 kV to 420 k, and their capacities ranging from 6.25 MVA to 300 MVA [6]. Among all the transformers in operation, there are 25,000 large and medium-sized natural ester transformers [6,7].The performance and property of insulating oil have a significant impact on the operation safety of the transformer. Almost one-third of the transformers' damage is caused by insulation problems, among which particles pollution of insulating oil is a significant factor [8]. The existence of impurities in transformer oil is inevitable. The sources of particles mainly include three parts [9-12]: The first part is from impurities left over during the production, assembly, and transportation of transformers, the second...