2008
DOI: 10.1002/pip.867
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Increase in external quantum efficiency of encapsulated silicon solar cells from a luminescent down‐shifting layer

Abstract: This paper reports the external quantum efficiency (EQE) of encapsulated screen-printed crystalline silicon solar cells, where the encapsulation includes a layer of luminescent down-shifting (LDS) molecules. At wavelengths less than 400 nm, the inclusion of the LDS molecules increases the EQE from near zero to, at most, 40%. The increase in EQE corresponds to a rise in short-circuit current density of 0Á37 W 0Á13 mA/cm 2 under the AM1-5g spectrum.

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Cited by 137 publications
(83 citation statements)
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“…There is also a large absorption of ultraviolet and blue light in the module covering glass. The utilization of the down shifting effect before the light enters the glass could improve the efficiency of the module considerably [24].…”
Section: Introductionmentioning
confidence: 99%
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“…There is also a large absorption of ultraviolet and blue light in the module covering glass. The utilization of the down shifting effect before the light enters the glass could improve the efficiency of the module considerably [24].…”
Section: Introductionmentioning
confidence: 99%
“…The one of the most straightforward methods of quantum dots application in photovoltaics is their utilization for light conversion in down-conversion (DC) process, which is also known as quantum-cutting [19][20][21][22][23][24][25]. The down-converter transforms one high energy photon into two or more photons of lower energy but simultaneously higher than the bandgap.…”
Section: Introductionmentioning
confidence: 99%
“…Van Sark et al [84] simulated the performance improvement of multicrystalline silicon cells with a PL photon converter containing CdSe quantum dots with center emission wavelengths of 603 nm and calculated an increase in shortcircuit current of nearly 10%. This low-cost adaptation has been shown to considerably improve the spectral response at high energies [86], increase the short-circuit current density [83], and result in improvements of cell efficiency of around 0.4-2% in absolute terms [86,87].…”
Section: Photoluminescence (Pl)mentioning
confidence: 99%
“…PL can also be used to enhance photosynthetic growth by shifting UV light into the PAR region, ideally into the blue region to match the absorption spike of chlorophyll, where it can be efficiently photosynthesized. Typically PL photon converters or luminescent down-shifters are fabricated by doping highly transparent polymers (e.g., polymethyl methacrylate (PMMA) or polyvinyl acetate (PVA)) with luminescent dyes [80][81][82][83], semiconductor quantum dots [63,84,85], or silicon nanocrystals [86]. The luminescent particles exhibit a Stokes shift, absorbing short wavelength radiation and emitting longer wavelengths.…”
Section: Photoluminescence (Pl)mentioning
confidence: 99%
“…This has been undertaken for a number of different solar cells including crystalline silicon (cSi) [8] [9], amorphous silicon [7], CdS/copper sulfide [7], CdS/CdTe [10][11] [12] and copper indium gallium selenide (CIGS) [13] [14], an extensive list including efficiency improvements can be found in [15].…”
Section: Introductionmentioning
confidence: 99%