2013
DOI: 10.1002/chem.201300164
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Incorporation of Pure Fullerene into Organoclays: Towards C60‐Pillared Clay Structures

Abstract: Dem Ruhekomplex auf der Spur: [{IrCp*Cl2}2] katalysiert die Redoxcyclisierung von Nitronalkinen wie 1 unter Bildung von Azomethinyliden, die anschließend mit Elektrophilen und π‐Bindungen umgesetzt werden können. Der ungewöhnliche O‐gebundene Azomethinkomplex 2 wurde isoliert und als Ruhezustand des Katalysators in der Azomethinylid‐Bildung identifiziert. Cp*=C5Me5.

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Cited by 7 publications
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“…This type of nanocomposites can be obtained by directly intercalating nanomaterials within the interlayer space of clay minerals (Gournis et al, 2004(Gournis et al, , 2006Tsoufis et al, 2013), or by in-situ transforming the pre-intercalated materials into nanomaterials (Ma et al, 2013;Ruiz-Hitzky et al, 2011;Xu et al, 2013;Zhang et al, 2012). Generally, the direct intercalation method is only applicable for very small nanomaterials, e.g., fullerene and its derivatives (Gournis et al, 2004, Applied Clay Science 100 (2014 2006; Tsoufis et al, 2013). As such, the in-situ transformation method draws more attention (Fernandez-saavedra et al, 2008;Ruiz-Hitzky et al, 2011;Xu et al, 2013;Zhang et al, 2012).…”
Section: Introductionmentioning
confidence: 99%
“…This type of nanocomposites can be obtained by directly intercalating nanomaterials within the interlayer space of clay minerals (Gournis et al, 2004(Gournis et al, , 2006Tsoufis et al, 2013), or by in-situ transforming the pre-intercalated materials into nanomaterials (Ma et al, 2013;Ruiz-Hitzky et al, 2011;Xu et al, 2013;Zhang et al, 2012). Generally, the direct intercalation method is only applicable for very small nanomaterials, e.g., fullerene and its derivatives (Gournis et al, 2004, Applied Clay Science 100 (2014 2006; Tsoufis et al, 2013). As such, the in-situ transformation method draws more attention (Fernandez-saavedra et al, 2008;Ruiz-Hitzky et al, 2011;Xu et al, 2013;Zhang et al, 2012).…”
Section: Introductionmentioning
confidence: 99%