2001
DOI: 10.1021/cm000519u
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Inclusion of Poly(tetramethyl-p-phenyl- enediamine dihydrochloride) into MoO3:  A Cooperative Formation Route to Construct a Polymer/MoO3 Layered Structure

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Cited by 27 publications
(5 citation statements)
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“…Molybdenum bronze, a long-known mixed-valent metal oxide colored material, was first reported by Alfred Stavenhagen and E. Engels in 1895 and is nothing but a hydronium- or hydrated-alkali-metal-cation-inserted MoO 3 compound. Even though the literature of MoO 3 is vast for MoO 3 intercalations, we did not come across any MoO 3 material intercalated with a transition metal–aqua coordination complex. In the present work, we could synthesize a hitherto unknown α-MoO 3 -intercalated {Ni­(H 2 O) 6 } 2+ compound, [Mo VI 2 O 6 (CH 3 COO)­{Ni II (H 2 O) 6 } 0.5 ]·H 2 O ( 1 ), in a simple one-pot wet synthesis and characterize this composite by single-crystal X-ray crystallography.…”
mentioning
confidence: 66%
“…Molybdenum bronze, a long-known mixed-valent metal oxide colored material, was first reported by Alfred Stavenhagen and E. Engels in 1895 and is nothing but a hydronium- or hydrated-alkali-metal-cation-inserted MoO 3 compound. Even though the literature of MoO 3 is vast for MoO 3 intercalations, we did not come across any MoO 3 material intercalated with a transition metal–aqua coordination complex. In the present work, we could synthesize a hitherto unknown α-MoO 3 -intercalated {Ni­(H 2 O) 6 } 2+ compound, [Mo VI 2 O 6 (CH 3 COO)­{Ni II (H 2 O) 6 } 0.5 ]·H 2 O ( 1 ), in a simple one-pot wet synthesis and characterize this composite by single-crystal X-ray crystallography.…”
mentioning
confidence: 66%
“…The stoichiometry is similar with reported (polymer) x MoO 3 hybrids, such as (polyaniline) 0.24 MoO 3 [ 22 ] and [poly(tetramethyl‐p‐phenylenediamine dihydrochloride)] 0.23 MoO 3 . [ 23 ] Thus, it can be concluded that the sample PEDOT‐MoO 3 is composed of Mo‐O layered sheets, a monolayer of PEDOT chains, and H 2 O molecules within the MoO 3 interlamellar spacings.…”
Section: Resultsmentioning
confidence: 99%
“…The intercalation science of layered molybdenum trioxide (α-MoO 3 ) opens an exciting field for tuning their structural, physical, and chemical properties. Diverse guest species, including organic and inorganic materials, have been intercalated into these layers, resulting in “intercalated MoO 3 ” materials. Above all, the intercalation of alkali ions into layered MoO 3 has been strongly documented and widely used as efficient energy storage and electrochemical systems . Interestingly, the intercalation of any proton or alkali ion into layered MoO 3 leads to the formation of reduced molybdenum trioxide (MoO 3– x ), so-called molybdenum bronze (shiny and lustrous material). Being versatile structures with a wide range of physical and chemical properties, MoO 3 gains enormous attention for its application as optical, electronic, catalytic, bio, and energy materials .…”
Section: Introductionmentioning
confidence: 99%