Inclusion Compounds ? possibility of their combination and use in different branches of chemistry

Sopková, Anna

doi:10.1007/bf01041361

Cited by 14 publications

(2 citation statements)

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“…[19] One amongst the other decomposition products of CL20 is CO 2 , which was identified as a guest molecule within CL20 crystal lattices during the heating and simultaneous decomposition of a particular polymorph of CL20 (e-CL20). [20] However, except Fourier transform infra red spectroscopy (FTIR) analysis, no report to date is made about any characterization of the potential new inclusion compound CL20-CO 2 .…”

Section: Introductionmentioning

confidence: 99%

“…[1,2] Some of the most well-known host systems are supramolecular organic materials, such as cyclodextrins [2,3] and calixarenes, [4] which are of particular interest to selectively trap small organic molecules for enantiomer separation and recognition, [5] active substance delivery, [6] or polymerization in matrices. [7] Organic crystals as guests for host molecules [8] are yet another example of these complex systems, being considered as a prototype example of multicomponent self-organization.…”

Section: Introductionmentioning

confidence: 99%

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Host–Guest Inclusion Compound from Nitramine Crystals Exposed to Condensed Carbon Dioxide

Martin

Marre

Guionneau

et al. 2010

Chemistry A European J

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HNIW or CL20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane) is a nitramine, which is considered as the highest energetic molecular compound known to date, therefore, attracting increasing interest in propulsion applications. Additionally, CL20 is an interesting system for fundamental studies, exhibiting several polymorphs, which can behave as host lattices for trapping guest molecules. Herein, a new CL20 structure that contains inserted CO(2) molecules is reported. A combination of Fourier transform infra red (FTIR) spectroscopy, scanning electron microscopy (SEM), single-crystal X-ray diffraction, and thermal analyses (thermogravimetric analysis coupled with mass spectrometry and differential scanning calorimetry) was used to characterize this new material.

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Section: Introductionmentioning

confidence: 99%