2018
DOI: 10.1111/jace.16225
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In situ synthesis of three‐dimensional nanofiber‐knitted ceramic foams via reactive sintering silicon foams

Abstract: Three-dimensional ceramic nanofiber-assembled materials with large specific surface area and excellent thermal insulation properties are attracting increasing interests for their unique structure and promising applications. In this paper, we propose a facile methodology to fabricate three-dimensional silicon nitride nanofiber-knitted ceramic foams via in situ reactive synthesis from silicon foams. Silicon particle-stabilized foams are fabricated for the first time using long-chain surfactant cetyltrimethyl amm… Show more

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Cited by 15 publications
(5 citation statements)
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“…The self-assembly of powder particles at the air-water interface during the particle-stabilized foaming process greatly weakens the bridging effect between powder particles. [49,50] In addition, the almost no-linear shrinkage of the equiaxed grains constituting the fragments during sintering will further reduce porosity at the grain boundaries. [51,52] Using equiaxed grains as seeds to replace powder particles for hot-pressing sintering not only improves the relative density and flexural strength of bulk ceramics, but also increases the fracture toughness by coarsening to form plate-like grains induced by additives.…”
Section: Resultsmentioning
confidence: 99%
“…The self-assembly of powder particles at the air-water interface during the particle-stabilized foaming process greatly weakens the bridging effect between powder particles. [49,50] In addition, the almost no-linear shrinkage of the equiaxed grains constituting the fragments during sintering will further reduce porosity at the grain boundaries. [51,52] Using equiaxed grains as seeds to replace powder particles for hot-pressing sintering not only improves the relative density and flexural strength of bulk ceramics, but also increases the fracture toughness by coarsening to form plate-like grains induced by additives.…”
Section: Resultsmentioning
confidence: 99%
“…A schematic diagram of its microsphere formation is shown in Figure 5 . Huo [ 53 ] sintered silicon nitride nanofiber knitted ceramic foam by an in situ reaction on the basis of a stable silicon foam. This new silicon carbide ceramic foam consists of a three-dimensional nanofiber assembly network with a diameter of 15–100 nm.…”
Section: Ceramic Nanofibersmentioning
confidence: 99%
“…Moreover, BN exhibits a high thermal conductivity, a desired mechanical property and is electrically insulator, so can be widely used for structural, thermal, electrical, and optical applications. Silicon nitride (Si 3 N 4 ) is another nitride ceramic compound which is widely applied in fiber preparation [91][92][93]. GaN fiber, as an important functional fiber, shows great application potential in semiconductor devices [94].…”
Section: Materials For Preparation Of Fcfsmentioning
confidence: 99%