In situ syntheses, crystal structures and magnetic properties of Cu^IIand Mn^IIcoordination assemblies based on a novel heteroalicyclic dicarboxylate tecton and N-donor co-ligands

FeII, CoII and NiII complexes based on 1-chloro-3-(pyridin-2-yl)imidazo[1,5-a]pyridine: synthesis, structures, single-molecule magnetic and electrocatalytic properties

“…In recent several decades, enormous efforts have been dedicated to the design and synthesis of 3d metal-based SMMs supported by N-containing heterocyclic ligands. 5 The complexes formed by 3d transition metal ions usually possess unquenched orbital angular momentum, leading to high magnetic anisotropy. Moreover, N-containing heterocyclic ligands have received intense attention due to their strong coordination affinity to the first-row transition metal ions 6 and their diverse coordination modes.…”