In situ polymerization of ethylene in the presence of graphene by α‐diimine Nickel (II)/MAO catalyst system: Thermal and rheological study

Abstract

In situ polymerization of ethylene with pretreated graphene nano‐platelet (GNP) was carried out by (α‐diimine nickel)/MAO catalyst system. The molecular weight of the synthesized samples was determined using rheometric mechanical spectroscopy. The number of branches and melting temperature values was evaluated by regular differential scanning calorimetry (DSC) and successive self‐nucleation and annealing (SSA) technique. According to obtained results, the molecular weight of the samples was increased from 72,730 to 260,100 g/mol for neat PE and high‐filled GNP, respectively. The number of chain branches decreased by the addition of GNP from 61.51 per 1,000 carbon atoms to 37.10 for neat PE and the sample containing 22.36 wt% of GNP. Obtained results revealed that the samples containing low branches and high molecular weight were achieved in the presence of highly loaded GNP. Also, the electrical conductivity, storage modulus, loss modulus, and complex viscosity of the samples improved by increasing GNP weight fraction.

Positive Temperature Coefficient and Electrical Conductivity Investigation of Hybrid Nanocomposites Based on High‐Density Polyethylene/Graphene Nanoplatelets/Carbon Black

“…[ 6–8 ] However, in situ polymerization and solution casting have been recognized as effective ways of nanocomposite manufacturing to achieve good dispersion of nanoparticles. [ 9,10 ] The melt‐mixing method has some other advantages like cost effectiveness, rapid processing, and being an industry favorite. [ 11,12 ] Thus, the melt‐mixing technique could be regarded as a prevalent method among different techniques of nanocomposite manufacturing.…”