In situ hydrothermal synthesis of a twofold entangled coordination network based on tetranuclear zinc(II) clusters: An experimental and theoretical study

Huang, Rong‐Yi; Xue, Chengshan; Wang, Zhu-Qinq; Xu, Heng; Wu, Guangxin; Ye, Shiyong

doi:10.1016/j.ica.2013.06.024

Cited by 9 publications

(3 citation statements)

References 36 publications

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“…Some of these showed 2D to 3D inclined polyrotaxane forms, which will be included in the next part of this section. Many other related examples are also decorated in the literature. ,,− …”

Section: Different Entanglementsmentioning

confidence: 99%

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

et al. 2021

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Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular nature and tunable structures. These factors enable a number of properties and applications, including gas and guest sorption, storage and separation of gases and small molecules, catalysis, luminescence, sensing, magnetism, and energy storage and conversion. Among MOFs, two-dimensional (2D) compounds are also known as 2D CPs or 2D MOFs. Since the discovery of graphene in 2004, 2D materials have also been widely studied. Several 2D MOFs are suitable for exfoliation as ultrathin nanosheets similar to graphene and other 2D materials, making these layered structures useful and unique for various technological applications. Furthermore, these layered structures have fascinating topological networks and entanglements. This review provides an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.

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Section: Different Entanglementsmentioning

confidence: 99%

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

et al. 2021

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“…The functionality of CPs is closely related to their structures. [6][7][8] Therefore, an in-depth understanding of the relationship between structure and function can help us design and synthesize CPs with specific functions. In order to construct CPs with desired structures, the judicious selection of appropriate organic building blocks with polydentate coordination sites and central metal ions with unique coordination geometries could be helpful for the construction of novel coordination framework.…”

Section: Introductionmentioning

confidence: 99%

“…As is well known, hydro(solvo)thermal self‐assembly technique has become an effective method to obtain the crystalline CPs. The functionality of CPs is closely related to their structures [6–8] . Therefore, an in‐depth understanding of the relationship between structure and function can help us design and synthesize CPs with specific functions.…”

Section: Introductionmentioning

confidence: 99%

Three new V‐shape dicarboxylate coordination polymers: syntheses, crystal structures and properties

Chen

2021

Zeitschrift anorg allge chemie

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Three new coordination polymers (CPs) with the formulas of [Zn 2 (SDBA) 2 (im) 4 ] n (1), [CdCa(SDBA) 2 (DMA)(H 2 O)] n • 2n(DMA) (2) and [Cu(SDBA) 0.5 (μ 2 -OH)] n (3) (H 2 SDBA = 4,4'-dicarboxybiphenyl sulfone, im = imidazole, DMA = N,N'-dimethylacetamide) have been synthesized under hydro(solvo)thermal conditions and characterized by elemental analyses, powder x-ray diffraction analyses, thermogravimetric analyses and single crystal X-ray structural analyses. CP 1 displays a 1D double chain structure consolidated by NÀ H•••O hydrogen bonds, which are further extended into a 3D supramolecular framework via the help of intermolecular NÀ H•••O hydrogen bonds. CP 2 features a 2D layered structure based on 1D À [CdÀ (COO) 2 À Ca] n À chains. Interestingly, in this 2D layer there exists large 1D channels that are occupied by the coordinated DMA molecules, coordinated water molecules and free DMA molecules. CP 3 has a 3D framework based on 1D À [CuÀ (COO)(μ 2 -OH)À Cu] n À chains. The luminescent properties of CPs 1 and 2, gas adsorption properties of 2 a (solvent-free form of CP 2), and photocatalytic property of CP 3 were also investigated.

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Synthesis, structural and magnetic investigation of copper(II) coordination polymer based on 5-amino-tetrazolate and isonicotinate mixed ligands

Chen

et al. 2014

Inorganica Chimica Acta

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In situ hydrothermal synthesis of a twofold entangled coordination network based on tetranuclear zinc(II) clusters: An experimental and theoretical study

Cited by 9 publications

References 36 publications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

Three new V‐shape dicarboxylate coordination polymers: syntheses, crystal structures and properties

Synthesis, structural and magnetic investigation of copper(II) coordination polymer based on 5-amino-tetrazolate and isonicotinate mixed ligands

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