In situ growth of copper nanoparticles on multiwalled carbon nanotubes and their application as non-enzymatic glucose sensor materials

Wu, Huixia; Cao, Wei-Man; Li, Yan; Liu, Gang; Wen, Ying; Yang, Haifeng; Yang, Sen

doi:10.1016/j.electacta.2010.02.017

Cited by 225 publications

(95 citation statements)

References 44 publications

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“…Furthermore, it has been described that, at potentials more than 400 mV versus Ag/AgCl, an oxidation of Cu 2+ to Cu 3+ occurs [29], while the cathodic peak can be attributed to the reduction of Cu 3+ . The sudden increased current density at a potential of about 350 mV versus Hg/HgSO4 is connected with a complete oxidation of cuprite.…”

Section: Amperometric Sensing Performance Of Glucosementioning

confidence: 99%

Facile wet-chemical synthesis of differently shaped cuprous oxide particles and a thin film: Effect of catalyst morphology on the glucose sensing performance

Neetzel

Muench

Matsutani

et al. 2015

Sensors and Actuators B: Chemical

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In this work, different facile synthesis routes were developed to create cuprite-based catalyst systems for the amperometric detection of glucose, allowing us to evaluate the impact of important electrode fabrication parameters on the glucose sensing performance. Using homogenous precipitation routes based on a redox system, two differently shaped cuprite particles-skeletons and polyhedrons-could be obtained. Furthermore, a novel electroless deposition technique was introduced that does not require sensitization and activation pretreatments, allowing for the direct modification of the glassy carbon. This technique produced electrodes with dense thin film consisting of merged, octahedral cuprite crystals. Afterward, these materials were tested as potential catalysts for the electrochemical detection of glucose. While the catalyst powders obtained by precipitation required Nafion ® to be attached to the electrode, the thin film synthesized using electroless plating could be realized with and without additive. Summarizing the results, it was found that Nafion ® was not required to achieve glucose selectivities typically observed for cuprite catalysts. Also, the type of catalyst application (direct plating versus ink drop coating) and the particle shape had a pronounced effect on the sensing performance. Compared to the thin film, the powder-type materials showed significantly increased electrochemical responses. The best overall performance was achieved with the polyhedral cuprite particles, resulting in a high sensitivity of 301 µA . mmol -1 cm -2 , a linear range up to 298 µmol . L -1 and a limit of detection of 0.144 µmol . L -1 .2

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Section: Amperometric Sensing Performance Of Glucosementioning

confidence: 99%

Facile wet-chemical synthesis of differently shaped cuprous oxide particles and a thin film: Effect of catalyst morphology on the glucose sensing performance

Neetzel

Muench

Matsutani

et al. 2015

Sensors and Actuators B: Chemical

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“…Research into enzyme-mimicking materials is typically focused on addressing significant issues such as fouling and selectivity (16). In this regard, combinations of ILs, CNTs, or graphene with metal nanomaterials seem a promising approach for the nonenzymatic detection of glucose (16,209,(283)(284)(285)(286)(287). Zhu et al (288) studied the role of ILs in composites prepared by embedding Au-NPs in bucky-gels.…”

Section: Tailoring Nanocomposites For Biomedical Applicationsmentioning

confidence: 99%

Properties and Customization of Sensor Materials for Biomedical Applications

Zuliani¹,

Curto²,

Matzeu³

et al. 2014

Comprehensive Materials Processing

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“…In order to address the correspondence problems, reliable, sensitive and selective non-enzymatic strategies for the development of electrochemical glucose sensors were established. According to the previous literatures, many materials, including noble metals [9], metal oxides [10] and carbonbased materials [11], have been used to improve the electrocatalytic activity to the oxidation of glucose. For example, Chang et al synthesized a Pt nanoclusters/ graphene nanocomposite for non-enzymatic glucose sensing [12], and a non-enzymatic glucose sensor based on rGO/Ni(OH) 2 composites modified electrode was developed by Subramanian et al [13].…”

Section: Introductionmentioning

confidence: 99%

Copper‐based Metal‐organic Framework for Non‐enzymatic Electrochemical Detection of Glucose

Sun

Wang

et al. 2018

Electroanalysis

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A non-enzymatic electrochemical glucose sensor based on a Cu-based metal-organic framework (Cu-MOF) modified electrode was developed. The Cu-MOF was prepared by a simple ionothermal synthesis, and the characterizations of the Cu-MOF were studied by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), single-crystal X-ray powder diffraction (SCXRD), and X-ray powder diffraction (XRD). Electrochemical behaviors of the Cu-MOF modified electrode to glucose were measured by differential pulse voltammetry (DPV). The electrochemical results showed that the Cu-MOF modified electrode exhibited an excellent electro-catalytic oxidation towards glucose in the range of 0.06 mM to 5 mM with a sensitivity of 89 mA/mM cm 2 and a detection limit of 10.5 nM. Moreover, the fabricated sensor showed a high selectivity to the oxidation of glucose in coexistence with other interferences. The sensor was satisfactorily applied to the determination of glucose in urine samples. With the significant electrochemical performances, MOFs may provide a suitable platform in the construction of kinds of electrochemical sensors and/or biosensors and hold a great promise for sensing applications.

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In situ growth of copper nanoparticles on multiwalled carbon nanotubes and their application as non-enzymatic glucose sensor materials

Cited by 225 publications

References 44 publications

Facile wet-chemical synthesis of differently shaped cuprous oxide particles and a thin film: Effect of catalyst morphology on the glucose sensing performance

Facile wet-chemical synthesis of differently shaped cuprous oxide particles and a thin film: Effect of catalyst morphology on the glucose sensing performance

Properties and Customization of Sensor Materials for Biomedical Applications

Copper‐based Metal‐organic Framework for Non‐enzymatic Electrochemical Detection of Glucose

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