In situ generated polymer electrolyte coating-based Janus interfaces for long-life LAGP-based NMC811/Li metal batteries

Stabilizing the Li1.4Al0.4Ti1.6(PO4)3/Li interface with an in situ constructed multifunctional interlayer for high energy density batteries

“…With the modification, the symmetric cells stably cycled for over 1000 h with a low polarization voltage at a current density of 0.1 mA cm −2 . Chen et al 20 developed a Janus interface for coating Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 by the in situ generated polymer. The in situ crosslinked polymer delivered good interfacial compatibility with electrodes, which ensured more than 200 cycles for modified full cells with the NCM811 cathode.…”

Progress in the development of solid-state electrolytes for reversible room-temperature sodium–sulfur batteries

“…135 Overall, the ionic conduction in ISEs depends on the availability of defects/vacancies, the presence of mobile ions, and their energy. 136 ISE follows Arrhenius model ionic conduction concerning temperature; this is mainly attributed to the relatively fixed orientations of molecules, which occupy equilibrium positions in a solid. 137,138 In the Arrhenius model for ionic conduction in solids, data are generated by varying the temperature and temperature-dependent ionic conduction, which are further equated.…”

Tailoring Practically Accessible Polymer/Inorganic Composite Electrolytes for All-Solid-State Lithium Metal Batteries: A Review

“…Polymer electrolyte coatings not only kept PIEs in contact with the electrode, accelerating the interfacial ion transport kinetics, but also built stable CEI and SEI layers. The PIEs enabled the Li||LiNi 0.8 Mn 0.1 Co 0.1 O 2 cells to have outstanding cycle stability at 4.5 V [ 196 ]. Yang et al developed PIEs with “brick–mortar” microstructures (Fig.…”

“…Copyright 2019, Elsevier. b Comparison of interfacial evolution in a liquid electrolyte, ex situ polymer modification and in situ Janus polymer modification [ 196 ]. Copyright 2022, Elsevier.…”