In Situ Fabrication of Highly Dispersed Co-Fe-Doped-Δ-Mno2 Catalyst by a Facile Redox-Driving Mofs-Derived Method for Low-Temperature Oxidation of Toluene

Huang, Qianlin; Zhao, Puzhen; Wang, Weiwei; Lv, Lu; Zhang, Weiming; Pan, Bingcai

doi:10.2139/ssrn.4156086

Cited by 1 publication

(1 citation statement)

References 41 publications

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“…Meanwhile, we compared in situ DRIFTS of several literature studies on the catalytic degradation of toluene and found the similarities and differences. The degradation pathway of toluene proposed by Huang et al 55 is approximately the same as this work. The authors also confirm that benzoic acid species accumulate and consume more rapidly on the target catalysts.…”

Section: Mechanistic Exploration For Toluene Combustionsupporting

confidence: 52%

Expediting Toluene Combustion by Harmonizing the Ce–O Strength over Co-Doped CeZr Oxide Catalysts

Shen

Deng

et al. 2023

Environ. Sci. Technol.

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Low-temperature catalytic degradation of volatile organic compounds (VOCs) by enhancing the activity of non-precious metal catalysts has always been the focus of attention. The mineralization of aromatic VOCs requires the participation of a large number of oxygen atoms, so the activation of oxygen species is crucial in the degradation reaction. Herein, we originally adjust the Ce–O bond strength in CeZr oxide catalysts by cobalt doping to promote the activation of oxygen species, thus improving the toluene degradation performance while maintaining high stability. Subsequent characterizations and theoretical calculations demonstrate that the weakening of the Ce–O bond strength increases the oxygen vacancy content, promotes the activation of oxygen species, and enhances the redox ability of the catalysts. This strategy also promotes the activation of toluene and accelerates the depletion of intermediate species. This study will contribute a strategy to enhance the activation ability of oxygen species in non-noble metal oxide catalysts, thereby enhancing the degradation performance of VOCs.

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Section: Mechanistic Exploration For Toluene Combustionsupporting

confidence: 52%