In Situ Exfoliation Growth Strategy Realizing Controlled Synthesis of 3D to 2D MOF Materials as High-Performance Electrochemical Biosensors
Qiao Jiang,
Chen Chen,
Ning Chai
et al.
Abstract:metal−organic framework (MOF) nanosheets with large surface area, ultrathin thickness, and highly accessible active sites have attracted great research attention. Developing efficient approaches to realize the controllable synthesis of welldefined 2D MOFs with a specific composition and morphology is critical. However, it is still a significant challenge to construct thin and uniform 2D MOF nanosheets and resolve the reagglomeration as well as poor stability of target 2D MOF products. Here, an "in situ exfolia… Show more
A three-dimensional MOF featuring an anthracene dimer ligand analogous to 4,4′-bipyridine undergoes selective dimensional reduction into a two-dimensional framework that can be mechanically exfoliated.
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