In Situ Encapsulating α‐MnS into N,S‐Codoped Nanotube‐Like Carbon as Advanced Anode Material: α → β Phase Transition Promoted Cycling Stability and Superior Li/Na‐Storage Performance in Half/Full Cells

Liu, Dai‐Huo; Li, Wenhao; Zheng, Yanping; Cui, Zheng; Xin, Yan; Liu, Dao-Sheng; Wang, Jiawei; Zhang, Yu; Lü, Hong‐Yan; Bai, Feng‐Yang; Guo, Jin‐Zhi; Wu, Xing‐Long

doi:10.1002/adma.201706317

Cited by 171 publications

(96 citation statements)

References 40 publications

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“…The high S a , porous and N-doped carbon features can offer a lot of active sites and ion transport pathways, which is conducive to Li + /Na + mobility and transport kinetics. [31][32][33] The components of NiO@CÀ N NSs were determined by thermogravimetric analysis in air from RT to 1000°C at 10°C min À 1 ( Figure S2). The weight loss curve suggests a continuous decrease of 8.6 % at~200°C, which can be mainly attributed to removal of adsorbed moisture.…”

Section: Resultsmentioning

confidence: 99%

“…The EIS spectra consists of two partly conterminal semicircles at between high/ medium frequencies and a straight sloping line at lowfrequency regions. [9,31] Sometimes, the low-frequency limit used for measurement may be too high to allow Li + to diffuse in the solid, so there may be a lack of sloped straight lines at low frequencies (Figure 4f). [43] Taking the EIS data at RT as an example (Figure 4a), R e of the battery reflects the combined of among separator, electrolyte and electrodes.…”

Section: Resultsmentioning

confidence: 99%

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Two‐Dimensional NiO@C‐N Nanosheets Composite as a Superior Low‐Temperature Anode Material for Advanced Lithium‐/Sodium‐Ion Batteries

Bai

Liu

et al. 2020

ChemElectroChem

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Most of the anodes used in lithium‐/sodium‐ion batteries (LIBs/SIBs) have poor low‐temperature (LT) performances, which severely limit their applications under LT environment. Herein, two‐dimensional nickel oxide nanosheet encapsulated in N‐doped carbon coated layer (abbreviated as NiO@C−N NSs) is successfully prepared and investigated for the first time as a LT anode for LIBs/SIBs. As a result, the prepared NiO@C−N NSs electrode delivers a high room temperature (RT) Li‐storage capacity (1036 mA h g−1 at 0.05 A g−1) and excellent LT Li‐storage performance (428 mA h g−1 at 0.05 A g−1 at −40 °C). Furthermore, the prepared NiO@C−N NSs also exhibits a superior RT Na‐storage capacity of 529 mA h g−1 at 0.05 A g−1 and superior LT Na‐storage performance. Through electrochemical impedance spectroscopy analysis, we find that the LT Li‐/Na‐storage performances of NiO@C−N NSs electrodes are mainly dominated by the RSEI of SEI membrane formation at the electrode/electrolyte interface. Moreover, the LT Li‐/Na‐storage properties of NiO@C−N NSs can be effectively improved by using commercial LT electrolyte with low viscosity and low melting point.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Two‐Dimensional NiO@C‐N Nanosheets Composite as a Superior Low‐Temperature Anode Material for Advanced Lithium‐/Sodium‐Ion Batteries

Bai

Liu

et al. 2020

ChemElectroChem

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“…[33][34][35] i ¼ av b ð2Þ Where i and v represent the currenta nd sweep rate, respectively,a nd a and b refer to constants. Consequently,t he b value of Fe 2 O 3 /GR can be quantified from the plots of log i versus log v for peaks 1a nd 2( 0.96 and 0.93, Figure 4b), [36,37] giving av alue approaching1 .0, [38,39] suggesting the kinetics of lithiation/delithiation are dominated by capacitive behavior. [40,41] The corresponding ratios of contribution can be quantified according to the Equations (4) and (5).…”

Section: Resultsmentioning

confidence: 99%

Advanced Li‐Ion Batteries with High Rate, Stability, and Mass Loading Based on Graphene Ribbon Hybrid Networks

Zhang

Wei

Jiang

et al. 2019

Chemistry A European J

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To optimize the cycle life and rate performance of lithium-ion batteries (LIBs), ultra-fine Fe 2 O 3 nanowires with a diameter of approximately 2nmu niformly anchoredo na cross-linked graphene ribbon network are fabricated. The unique three-dimensional structure can effectively improve the electrical conductivity and facilitate ion diffusion,e specially cross-plane diffusion. Moreover,F e 2 O 3 nanowires on graphene ribbons( Fe 2 O 3 /GR) are easilya ccessible for lithium ions compared with the traditional graphene sheets (Fe 2 O 3 / GS). In addition, the well-developed elastic network can not only undergo the drastic volume expansionduring repetitive cycling, but also protect the bulk electrode from further pulverization. As ar esult,t he Fe 2 O 3 /GR hybrid exhibits high rate and long cycle life Li storagep erformance (632 mAh g À1 at 5Ag À1 ,a nd 471 mAh g À1 capacity maintained even after 3000 cycles). Especially at high mass loading(% 4mgcm À2 ), the Fe 2 O 3 /GR can still deliver higher reversible capacity (223 mAh g À1 even at 2Ag À1 )c ompared with the Fe 2 O 3 /GS (37 mAh g À1 )f or LIBs.Scheme1.Schematicoft he synthesis procedureofF e 2 O 3 nanowires anchored on GR, and the corresponding Li ion transfer pathwaysf or Fe Supporting information and the ORCID identification number(s) for the author(s) of this article can be found under: https://doi.

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“…When evaluated as negative electrode material for SIBs, the NiS 2 nanospheres deliver a capacity of 319 mAh g −1 at 0.5 A g −1 for the 1000th cycle and a reversible capacity of 253 mAh g −1 at 5 A g −1 . Recently, Liu et al synthesized α‐MnS@N,S–NTC composite and tested its sodium storage performance. The as‐prepared α‐MnS@N,S–NTC composite shows the 1D nanostructure with the length of 0.5–1 µm and diameter of 100 nm.…”

Section: Conversion‐type Anode Materials For Sodium‐ion Batteriesmentioning

confidence: 99%

Nanostructured Conversion‐Type Negative Electrode Materials for Low‐Cost and High‐Performance Sodium‐Ion Batteries

Wei

Wang

Tan

et al. 2018

Adv Funct Materials

146

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Emerging sodium-ion batteries (SIBs) have attracted a great attention as promising energy storage devices because of their low cost and resource abundance. Nevertheless, it is still a major challenge to develop anode materials with outstanding rate capability and excellent cycling performance. Compared to intercalation-type anode materials, conversion-type anode materials are very potential due to their high specific capacity and low cost. A new insight and summary on the recent research advances on nanostructured conversion-type anode materials for SIBs is provided herein. The corresponding synthesis methods, sodium storage properties, electrochemical mechanisms, advanced techniques on studying the crystal structures, and optimization strategies for high-performance batteries are presented. Finally, the remaining challenges and perspectives for the future development of conversion-type anode materials in the energy storage fields are proposed. Figure 17. a) Time-lapse images showing the evolution of morphology of a CuO NW at an applied voltage of −3 V during the first sodiation process. b,c) In situ TEM images showing the 1st sodiation and the 1st desodiation of the single SnO 2 nanowire, respectively. d) Time-resolved TEM images from video frames show morphology and structure evolution as a function of sodiation time and its electron diffraction (ED) patterns. Schematic and structural evolution of e,f) the V 2 O 3 ⊂C-NTs and g,h) V 2 O 3 ⊂C-NTs⊂rGO electrodes observed by in situ TEM experiments, respectively, during constant potential discharge at 5 V. i,k) The morphology evolution of two α-MoO 3 nanobelts during the first sodiation process in a low magnification, in which the red arrows denote the reaction front. j) The measured relationship between the sodiation front position and the sodiation time for above two α-MoO 3 nanobelts. l) Time-resolved TEM images from video frames show the sodiation process of an individual Co 9 S 8 -filled CNT with an open end. All scale bars are 200 nm. m) Time-resolved TEM images from video frames reveal the appearance of fractures during the electrochemical sodiation process of an individual Co 9 S 8 -filled CNT with closed ends. All scale bars are 100 nm. n) Schematic showing the setup of the in situ experiment. HAADF-STEM images showing o) pristine and p) sodiated FeF 2 NPs and q) cropped time-lapse frames throughout the sodiation process. a) Reproduced with permission. [131]

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In Situ Encapsulating α‐MnS into N,S‐Codoped Nanotube‐Like Carbon as Advanced Anode Material: α → β Phase Transition Promoted Cycling Stability and Superior Li/Na‐Storage Performance in Half/Full Cells

Cited by 171 publications

References 40 publications

Two‐Dimensional NiO@C‐N Nanosheets Composite as a Superior Low‐Temperature Anode Material for Advanced Lithium‐/Sodium‐Ion Batteries

Two‐Dimensional NiO@C‐N Nanosheets Composite as a Superior Low‐Temperature Anode Material for Advanced Lithium‐/Sodium‐Ion Batteries

Advanced Li‐Ion Batteries with High Rate, Stability, and Mass Loading Based on Graphene Ribbon Hybrid Networks

Nanostructured Conversion‐Type Negative Electrode Materials for Low‐Cost and High‐Performance Sodium‐Ion Batteries

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