“…The degradation of the quartz crystal resonator during hydrogen absorption has already been reported [1,8,9,12]. The conclusion is that prolonged potential cycling in the hydrogen region should be avoided when EQCM is used in studies on hydrogen absorption/desorption.…”
Section: Resultsmentioning
confidence: 84%
“…In the literature [9][10][11][12][13]15], the data collected by EQCM are often interpreted with the use of a parameter in units of gram per mole, called ''apparent molar mass'', M a . For hydrogen absorption the value of M a is equal:…”
Section: Eqcm Studies On Pd Alloysmentioning
confidence: 99%
“…In general, the EQCM response can be determined by several factors [16][17][18] but in the case of hydrogen electrosorption the most important are two of them: (i) electrode mass changes (i.e. changes in the amount of electrosorbed hydrogen) and (ii) stresses in crystal lattice induced by hydrogen absorption [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15]19,20]. Therefore, the following equation is valid [6,14,15]:…”
Section: Introductionmentioning
confidence: 99%
“…In the literature, there are numerous reports devoted to the application of the electrochemical quartz crystal microbalance (EQCM) in the investigation of hydrogen absorption in Pd [1][2][3][4][5][6][7][8][9][10][11][12] and some of its alloys [13][14][15].…”
“…The degradation of the quartz crystal resonator during hydrogen absorption has already been reported [1,8,9,12]. The conclusion is that prolonged potential cycling in the hydrogen region should be avoided when EQCM is used in studies on hydrogen absorption/desorption.…”
Section: Resultsmentioning
confidence: 84%
“…In the literature [9][10][11][12][13]15], the data collected by EQCM are often interpreted with the use of a parameter in units of gram per mole, called ''apparent molar mass'', M a . For hydrogen absorption the value of M a is equal:…”
Section: Eqcm Studies On Pd Alloysmentioning
confidence: 99%
“…In general, the EQCM response can be determined by several factors [16][17][18] but in the case of hydrogen electrosorption the most important are two of them: (i) electrode mass changes (i.e. changes in the amount of electrosorbed hydrogen) and (ii) stresses in crystal lattice induced by hydrogen absorption [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15]19,20]. Therefore, the following equation is valid [6,14,15]:…”
Section: Introductionmentioning
confidence: 99%
“…In the literature, there are numerous reports devoted to the application of the electrochemical quartz crystal microbalance (EQCM) in the investigation of hydrogen absorption in Pd [1][2][3][4][5][6][7][8][9][10][11][12] and some of its alloys [13][14][15].…”
“…Electrochemical quartz crystal micro/-nanobalance is also a reported technique to survey water electrolysis catalysts. 1785 Firstly, demonstrated for very model Pd surfaces, 1791 it has since them been used for more practical nanostructured catalysts. [1792][1793][1794] Inductively coupled plasma mass spectrometry (ICP-MS), a classical technique for trace analyses, was recently coupled online to electrochemistry by the group of Mayrhofer.…”
Section: Physicochemical Techniques Coupled To Electrochemistry To Un...mentioning
Replacing fossil fuels with energy sources and carriers that are sustainable, environmentally benign, and affordable is amongst the most pressing challenges for future socio-economic development.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.