In situ derivatization hollow fibre liquid-phase microextraction for the determination of biogenic amines in food samples

Saaid, Mardiana; Saad, Bahruddin; Ali, Abdussalam Salhin Mohamed; Saleh, Muhammad Idiris; Basheer, Chanbasha; Lee, Hian Kee

doi:10.1016/j.chroma.2009.04.091

Cited by 99 publications

(41 citation statements)

References 36 publications

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“…Also, the achieved LODs by our proposed method are comparable or better than those in the previous reported methods (Paleologos et al 2003;Ruiz-Jiménez and Luque de Castro 2006;Saaid et al 2009;Spizzirri et al 2013). Also, HS-SPME-IMS is faster than all mentioned methods in Table 3.…”

Section: Quantitative Analysissupporting

confidence: 77%

Determination of Histamine and Tyramine in Canned Fish Samples by Headspace Solid-Phase Microextraction Based on a Nanostructured Polypyrrole Fiber Followed by Ion Mobility Spectrometry

2017

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This paper describes the development of a simple, rapid, and selective method based on headspace solid-phase microextraction (HS-SPME) combined with ion mobility spectrometry (IMS) for the simultaneous determination of histamine (HIS) and tyramine (TYR) in the canned fish samples. The spectra interferences were eliminated by using a new alternate reagent gas and resulted in an increased sensitivity and selectivity of IMS technique. A dodecylbenzenesulfonate-doped polypyrrole coating was used as a fiber for HS-SPME method. The calibration curves were linear in the range of 30-300 ng g −1 (R 2 > 0.994). Limits of detection for HIS and TYR were 3 and 4 ng g −1 , respectively. The proposed method was successfully applied to determine HIS and TYR in different canned fish samples without derivatization steps. Method validation was conducted by comparing our results with those obtained through gas chromatographymass spectrometry method.

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Section: Quantitative Analysissupporting

confidence: 77%

Determination of Histamine and Tyramine in Canned Fish Samples by Headspace Solid-Phase Microextraction Based on a Nanostructured Polypyrrole Fiber Followed by Ion Mobility Spectrometry

2017

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“…The results from such increases in ionic strength, however, are difficult to predict, particularly when derivatization is involved where yields may differ even for similar analytes present in the same sample [34]. In some instances, possibly as a result of increased viscosity at high ionic strength, the highest yields occur in an absence of salt [35]. Although the salt solutions produced a large unresolved peak with early retention time that excluded determination of phenol at the lower concentrations, this peak did not interfere with the determination of alkylphenols or carboxylic acids.…”

Section: Effects Of Saltmentioning

confidence: 93%

Effect of Tetrabutylammonium Cation on Solid-Phase Analytical Derivatization as a Function of Analyte Lipophilicity

2011

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Analytical derivatizations (AD) can increase the sensitivity of analyses-including those with mass spectrometric detection-by as much as three orders of magnitude. The extra steps required, however, are a possible impediment to their use. To simplify AD we investigated solid-phase analytical derivatization (SPAD) of compounds with diverse structures by using pentafluorobenzyl bromide (PFBBr) as the reagent. Model compounds were organic acids (e.g. phenols, chlorophenols and carboxylic acids) which were simultaneously extracted and derivatized from 0.1 M NaOH onto a polystyrene-divinylbenzene resin (XAD-4) as their pentafluorobenzyl (PFB) derivatives. Test analytes ranged in molecular weight from 94 for phenol to 266 for pentachlorophenol and octanol-water partition coefficients (log P) values ranged from 1.48 for phenol to 7.15 for hexadecanoic acid. Under SPAD conditions, reaction rates rapidly increased with log P, but yields for less lipophilic compounds, although precise, were unacceptably low. Use of the tetrabutylammonium (TBA) cation as a phase transfer catalyst increased the yield of compounds with low log P; but, unexpectedly, as the log P of the analyte increased, the phase transfer catalyst caused a decrease in yield. The data from this study define the log P range of compounds that require TBA for optimal yield and the log P range of compounds for which TBA compromises yield. This insight led to a simple, two-step, one-pot technique that gave high yields of the PFB derivatives for the entire range of analytes studied. SPAD first extracted/derivatized the lipophilic analytes from aqueous solution onto the solid phase. Extraction/derivatization of the polar analytes followed upon addition of TBA to the reaction mixture. The PFB ethers and esters of the entire range of analytes were then eluted from the XAD-4. The two-step procedure was faster, used less reagent and required lower temperature than comparable methods in the literature. With the twostep procedure, pentafluorobenzylation of phenols and carboxylic acids from water gave yields in excess of 88% with the exception of phenol and pentachlorophenol which were recovered in 57 and 44%, respectively. For all analytes, relative standard deviations were below 15%. The effect of matrix on yield varied between zero and a decline in recoveries of approximately 20-30% depending on the analyte and concentrations of NaCl or humic acid. In the presence of matrix components relative standard deviations remained below 20%.

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“…Chemical derivatization together with solid-phase microextraction and GC or GC-MS was also established for the determination of aliphatic amines in water, human urine and air [13][14][15][16][17]. Recently, single-drop microextraction (SDME) has been shown to be an effective and harmless sample preparation technique as an alternative to the conventional extraction and concentration method including solid-phase extraction [18][19][20][21][22][23][24]. The new technique of headspace (HS) SDME technique was also employed to the GC analysis of aliphatic amines in water [25,26].…”

Section: Introductionmentioning

confidence: 99%

Development of single‐drop microextraction and simultaneous derivatization followed by GC‐MS for the determination of aliphatic amines in tobacco

Sha

Meng

Lin

et al. 2010

J of Separation Science

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In this work, for the first time, headspace (HS) single-drop microextraction and simultaneous derivatization followed by GC-MS was developed to determine the aliphatic amines in tobacco samples. In the HS extraction procedure, the mixture of derivatization reagent and organic solvent was employed as the extraction solvent for HS single-drop microextraction and in situ derivatization of aliphatic amine in the samples. Fast extraction and simultaneous derivatization of the analytes were performed in a single step, and the obtained derivatives in the microdrop extraction solvent were analyzed by GC-MS. The optimized experiment conditions were: sample preparation temperature of 80 degrees C and time of 30 min, HS extraction solvent (the mixture of benzyl alcohol and 2,3,4,5,6-pentafluorobenzaldehyde) volume of 2.0 microL, extraction time of 90 s. With the optimal conditions, the method validations were also studied. The method has good linearity (R(2) more than 0.99), accepted precision (RSD less than 13%), good recovery (98-104%) and low limit of detection (0.11-0.97 microg/g). Finally, the proposed technique was successfully applied to the analyses of aliphatic amines in tobacco samples of seven different brands. It was further demonstrated that the proposed method offered a simple, low-cost and reliable approach to determine aliphatic amines in tobacco samples.

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In situ derivatization hollow fibre liquid-phase microextraction for the determination of biogenic amines in food samples

Cited by 99 publications

References 36 publications

Determination of Histamine and Tyramine in Canned Fish Samples by Headspace Solid-Phase Microextraction Based on a Nanostructured Polypyrrole Fiber Followed by Ion Mobility Spectrometry

Determination of Histamine and Tyramine in Canned Fish Samples by Headspace Solid-Phase Microextraction Based on a Nanostructured Polypyrrole Fiber Followed by Ion Mobility Spectrometry

Effect of Tetrabutylammonium Cation on Solid-Phase Analytical Derivatization as a Function of Analyte Lipophilicity

Development of single‐drop microextraction and simultaneous derivatization followed by GC‐MS for the determination of aliphatic amines in tobacco

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