“…[1, 2, 3, 4] The complex physical properties include the unconventional superconductivity in water-intercalated Na 0.35 CoO 2 , [5] temperature-dependent Hall effect, [3,6] large negative MR in (Bi,Pb) 2 M 2 Co 2 O y (M=Sr and Ca) and Ca 3 Co 4 O 9 ,[2, 6,7] large thermopower (TEP) with low resistivity,[1, 2] and complicated magnetic structure, [8,9,10] etc. These triangular cobaltites have the common structural unit of CdI 2 -type hexagonal [CoO 2 ] layer, which is composed of edge-shared CoO 6 octahedra.…”