In‐Beam Mössbauer Spectroscopy Using A Radioisotope Beam and A Neutron Capture Reaction

Chemical species of localized fe atoms in solid hydrogen using in-beam mössbauer spectroscopy

“…[Fe(H 2 ) 2 ] + was considered to be produced by the reaction shown in Eq. (1). The reaction between a ground state Fe atom and H 2 molecules to form [Fe(H 2 ) 2 ] + was estimated to be exothermic, based on the ground states energies calculated by the ORCA program.…”

“…In-beam Mössbauer spectroscopy during implantation of short-lived 57 Mn of solids is a unique and useful tool for studying physical and chemical properties, e.g., oxidation states, electronic states, and coordination environments, of "extremely" dilute 57 Fe produced by βdecay of 57 Mn [1]. We have previously reported in-beam Mössbauer spectroscopy during 57 Mn implantation of several kinds of gas matrices to investigate the electronic states of Fe and the chemical species produced by reactions of Fe with gas molecules.…”